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利用氧化石墨的层离特性,采用化学还原法制备了石墨薄片材料,并采用红外光谱、X射线衍射、元素分析、透射电镜、原子力显微镜和扫描电镜对产品进行了表征和分析.结果表明,制备出的石墨薄片直径为1~3μm,厚度为2~4nm,为层状结构的非晶体,具有褶皱的固有属性,且极易发生团聚现象.

Graphite nanosheets are synthesized by chemical reduction method using the layer-separation characteristics of graphite oxide. The products are characterized by FT-IR, XRD, elementary analysis, TEM, AFM and SEM. The results show that the graphite nanosheets with a diameter of 1~3μm and the thickness of 2~4nm, are amorphous body with layered structure and corrugation morphology and easily aggregated together.

参考文献

[1] Kuznetsov V L;Chuvilin A L et al.Onion-like carbon from ultra-disperse diamond[J].Chemical Physics Letters,1994,222(04):343.
[2] Ying Chen;John Fitz Gerald;Lewis T. Chadderton;Laurent Chaffron .Nanoporous carbon produced by ball milling[J].Applied physics letters,1999(19):2782-2784.
[3] S. Orimo;G. Majer;T. Fukunaga;A. Zuttel;L. Schlapbach;H. Fujii .Hydrogen in the mechanically prepared nanostructured graphite[J].Applied physics letters,1999(20):3093-3095.
[4] 文潮,金志浩,关锦清,李迅,周刚,林俊德.炸药爆轰法制备纳米石墨粉[J].稀有金属材料与工程,2004(06):628-631.
[5] 陈国华,翁文桂,吴大军,吴丁财,陈晶晶,叶荔辉,颜文礼.石墨与聚苯乙烯的纳米复合过程研究[J].高分子学报,2001(06):803-806.
[6] 陈国华,吴翠玲,吴大军,翁文桂,黄双喜,林善旭.聚甲基丙烯酸甲酯/石墨薄片纳米复合及其导电性能研究[J].高分子学报,2003(05):742-745.
[7] 陈岁元,董维国,刘常升,宋学鹏.脉冲激光液相沉积法制备纳米石墨[J].东北大学学报(自然科学版),2002(11):1079-1082.
[8] 陈国华;方文焕 等.电化学插层法制备纳米石墨薄片[J].功能材料,1998,29(10):1236.
[9] Xu, YX;Bai, H;Lu, GW;Li, C;Shi, GQ .Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets[J].Journal of the American Chemical Society,2008(18):5856-5857.
[10] Si Y;Samulski ET .Synthesis of water soluble graphene[J].Nano letters,2008(6):1679-1682.
[11] Sasha Stankovich;Richard D. Finer;SonBinh T. Nguyen .Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(15):3342-3347.
[12] C. Nethravathi;Michael Rajamathi .Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(14):1994-1998.
[13] Scott Gilje;Song Han;Minsheng Wang .A Chemical Route to Graphene for Device Applications[J].Nano letters,2007(11):3394-3398.
[14] Nakajima T;Matsuo Y .Formation process and structure of graphite oxide[J].CARBON,1994,32(03):469.
[15] Bourlinos AB.;Gournis D.;Petridis D.;Szabo T.;Szeri A.;Dekany I. .Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6050-6055.
[16] Sasha Stankovich;Richard D.Piner;Xinqi Chen;Nianqiang Wu;SonBinh T.Nguyen;Rodney S.Ruoff .Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(2):155-158.
[17] Meyer J C;Geim A K et al.The structure of suspended graphene sheets[J].Nature,2007,446:60.
[18] He HY.;Forster M.;Lerf A.;Klinowski J. .A new structural model for graphite oxide[J].Chemical Physics Letters,1998(1/2):53-56.
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