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  4. 超级电容器用含氮多孔炭电极材料的研究进展

材料导报, 2011, 25(7): 24-32.

超级电容器用含氮多孔炭电极材料的研究进展

王晓娇 1, , 张传祥 2, , 邢宝林 3,

1.河南理工大学材料科学与工程学院,焦作,454003

2.河南理工大学材料科学与工程学院,焦作,454003

3.河南理工大学材料科学与工程学院,焦作,454003

基金项目:   河南理工大学博士基金(B2010-82)   河南省重点攻关项目(102102210207)  

关键词： 多孔炭 , 含氮官能团 , 负载方法 , 转化机制 , 电化学性能

Research Progress in the Nitrogen-containing Porous Carbon Electrode Materials for Supercapacitor

概述了表面改性和本体富氮两种负载氮原子的方法及其优缺点,总结了经高温处理后炭材料表面含氮官能团(N-6、N-5、N-Q、N-x)的转化机制:氮原予最终以化学性质稳定的六圆环的形式出现(如N-6、N-Q、N-x),温度高于600℃时,N-5(Pyrrolic-N)通过"扩环"作用转变为N-6、N-Q、N-X.最后从法拉第氧化还原反应(产生赝电容)和电极的湿润性两方面归纳了表面含氮官能团对超级电容器电化学性能的影响,并展望了今后的研究方向.

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