碳纳米管( CNTs)具有极高的杨氏模量、硬度和韧性、良好的导电性和导热性,但由于其分散性差,限制了其应用范围.超支化聚合物( HBP)具有低粘度、高流变性和良好的溶解性,特别是末端含有大量的活性官能团.用HBP修饰CNTs,不仅可以提高CNTs在聚合物基体中的分散性,改善CNTs与基体之间的相容性和界面粘接性能,还可以赋予CNTs新的功能.因此,综述了超支化聚合物改性CNTs的方法,包括直接改性法,表面引发聚合法等方法,并指出了每种改性方法的优缺点及其发展前景.
参考文献
[1] | U. Ritter;P. Scharff;G.E. Grechnev .Structure and magnetic properties of multi-walled carbon nanotubes modified with cobalt[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(13):4443-4448. |
[2] | 林嘉鹏,张海燕,陈易明,魏爱香,刘传标,陈雨婷.碳纳米复合对电极染料敏化太阳能电池的电化学性能[J].中国有色金属学报,2010(09):1753-1758. |
[3] | Zhou L J;Kang Y L;GuoJ G .Phenomenological model of interfacial stress transfer in carbon nanotubes reinforced composites with van der Waals effects[J].Polymer Composites,2011,32(07):1069. |
[4] | 王环颖,李文军,周花蕾,常志东,郭会超.非共价修饰碳纳米管吸附水中亚甲基蓝研究[J].功能材料,2011(01):96-99,103. |
[5] | Pucciariello, R.;Villani, V.;Giammarino, G. .Thermal behaviour of nanocomposites based on linear-low-density poly(ethylene) and carbon nanotubes prepared by high energy ball milling[J].Journal of Polymer Research,2011(5):949-956. |
[6] | Gao C;Muthukrishnan S;Li WW;Yuan JY;Xu YY;Muller AHE .Linear and hyperbranched glycopolymer-functionalized carbon nanotubes: Synthesis, kinetics, and characterization[J].Macromolecules,2007(6):1803-1815. |
[7] | Jiao-Tong Sun;Chun-Yan Hong;Cai-Yuan Pan .Surface modification of carbon nanotubes with dendrimers or hyperbranched polymers[J].Polymer chemistry,2011(5):998-1007. |
[8] | 廖峰,侯有军,曾幸荣.超支化聚合物在涂料中应用的研究进展[J].材料导报,2010(09):79-83. |
[9] | Wei Zhou;Jianwen Xu;Wenfang Shi .Surface modification of multi-wall carbon nanotube with ultraviolet-curable hyperbranched polymer[J].Thin Solid Films,2008(12):4076-4082. |
[10] | 周炜 .超支化聚合物改性碳纳米管及其纳米复合材料研究[D].中国科学技术大学,2008. |
[11] | 王国建,屈泽华,李岩,刘琳.超支化聚酯修饰多壁碳纳米管[J].应用化学,2007(07):828-831. |
[12] | 王国建,董玥,刘琳,许乾慰.超支化聚对氯甲基苯乙烯修饰碳纳米管表面的研究[J].高等学校化学学报,2007(01):164-168. |
[13] | Kumar I;Rode CV .Efficient synthesis of fused 1,2,3-triazolo-delta-lactams using Huisgen [3+2] dipolar cycloaddition "click-chemistry" in water[J].Chemistry Letters,2007(5):592-593. |
[14] | Nanda Gopal Sahoo;Sravendra Rana;Jae Whan Cho .Polymer nanocomposites based on functionalized carbon nanotubes[J].Progress in Polymer Science,2010(7):837-867. |
[15] | Indresh Kumar;Sravendra Rana;Chandrashakher V. Rode;Jae Whan Cho .Functionalization of Single-Walled Carbon Nanotubes with Azides Derived from Amino Acids Using Click Chemistry[J].Journal of nanoscience and nanotechnology,2008(7):3351-3356. |
[16] | Zhang, JX;Zheng, YP;Yu, PY;Mo, S;Wang, RM .The synthesis of functionalized carbon nanotubes by hyperbranched poly(amine-ester) with liquid-like behavior at room temperature[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(13):2953-2957. |
[17] | Sibdas Singha Mahapatra;Santosh Kumar Yadav;Jae Whan Cho .Synthesis and Characterization of Multi-Walled Carbon Nanotubes Functionalized with Hyperbranched Poly(urea-urethane)[J].Journal of nanoscience and nanotechnology,2010(12):8244-8253. |
[18] | Tomoki Ogoshi;Takayuki Saito;Tada-aki Yamagishi .Solubilization of single-walled carbon nanotubes by entanglements between them and hyperbranched phenolic polymer[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(1):117-123. |
[19] | Zdenko Spitalsky;Dimitrios Tasis;Konstantinos Papagelis .Carbon nanotube-polymer composites: Chemistry, processing, mechanical and electrical properties[J].Progress in Polymer Science,2010(3):357-401. |
[20] | 赵辉,罗小军,罗运军.超支化聚合物接枝改性碳纳米管及其分散性能[J].应用化学,2008(11):1361-1365. |
[21] | Choi JY;Oh SJ;Lee HJ;Wang DH;Tan LS;Baek JB .In-situ grafting of hyperbranched poly(ether ketone)s onto multiwalled carbon nanotubes via the A(3) + B-2 approach[J].Macromolecules,2007(13):4474-4480. |
[22] | Ja-Young Choi;Sang-Wook Han;Wan-Soo Huh .In situ grafting of carboxylic acid-terminated hyperbranched poly(ether-ketone) to the surface of carbon nanotubes[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(14):4034-4040. |
[23] | Yingkui Yang;Xiaolin Xie;Zhifang Yang .Controlled Synthesis and Novel Solution Rheology of Hyperbranched Poly(urea-urethane)-Functionalized Multiwalled Carbon Nanotubes[J].Macromolecules,2007(16):5858-5867. |
[24] | 丁顶 .化学修饰制备高水溶性碳纳米管[D].北京:北京化工大学,2007. |
[25] | Adeli, M;Mirab, N;Alavidjeh, MS;Sobhani, Z;Atyabi, F .Carbon nanotubes-graft-polyglycerol: Biocompatible hybrid materials for nanomedicine[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(15):3528-3536. |
[26] | Xu YY;Gao C;Kong H;Yan DY;Jin YZ;Watts PCP .Growing multihydroxyl hyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization[J].Macromolecules,2004(24):8846-8853. |
[27] | Hong CY;You YZ;Wu DC;Liu Y;Pan CY .Multiwalled carbon nanotubes grafted with hyperbranched polymer shell via SCVP[J].Macromolecules,2005(7):2606-2611. |
[28] | 杨应奎,邱胜强,王贤保,解孝林.碳纳米管的聚合物功能化与结构控制:聚合物接枝碳纳米管[J].化学进展,2010(04):684-695. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%