热解法制备KY3F10∶Yb3+、Tm3+纳米晶荧光标记材料

功能材料, 2011, 42(z4): 770-773.

热解法制备KY3F10∶Yb3+、Tm3+纳米晶荧光标记材料

王立强 ^1, , 彭勇 ^2, , 邢明铭 ^3, , 罗昔贤 ^4,

1.大连海事大学物理系,光电子技术研究所,辽宁大连116026

2.大连海事大学物理系,光电子技术研究所,辽宁大连116026

3.大连海事大学物理系,光电子技术研究所,辽宁大连116026

4.大连海事大学物理系,光电子技术研究所,辽宁大连116026

基金项目: 大连市科技计划资助项目(2010A17GX098) 国家自然科学基金资助项目(60979003)

关键词： KY3F10∶Yb3+、Tm3+纳米晶 , 荧光标记 , 上转换发光 , 热解法

Synthesis of nanoparticles KY3F10 : Yb3+ ,Tm3+ fluorescence label material by pyrolysis

采用热分解法制备了yb3+和Tm3+共掺杂的KY3F10∶Yb3+、Tm3+纳米晶,用X射线衍射(XRD)、透射电镜(TEM)和上转换光谱对样品进行了表征.研究了Tm3+浓度对样品的上转换发光性能的影响.结果表明制备的样品为类球形立方相KY3F10∶yb3+、Tm3+纳米晶,粒子尺寸分布均匀,平均粒径约为13nm左右.在980nm半导体激光器激发下,样品发射出蓝光(481nm)和红光(646nm),并且当Tm3+掺杂摩尔分数超过0.4％时,出现了浓度猝灭效应.发光强度与激发功率的关系表明,蓝光和红光的发光都是三光子过程.

参考文献

[1]	孙宝全,徐咏蓝,衣光舜,陈德朴.半导体纳米晶体的光致发光特性及在生物材料荧光标记中的应用[J].分析化学,2002(09):1130-1136.
[2]	Shen Jie;Sun Lingdong;Yan Chunhua.[J].Dalton Transactions,2008:5687-5697.
[3]	Wang L;Yah R;Huo Z et al.[J].Angewandte Chemie International Edition,2005,44(37):6054-6057.
[4]	Lim SF;Riehn R;Ryu WS;Khanarian N;Tung CK;Tank D;Austin RH .In vivo and scanning electron microscopy imaging of upconverting nanophosphors in Caenorhabditis elegans[J].Nano letters,2006(2):169-174.
[5]	Boyer John-christopher;Vetrone Fiorenzo;Cuccia Louis A et al.[J].Journal of the American Chemical Society,2006,128:7444-7445.
[6]	Niu Wenbin;Wu Suli;Zhang Shufen et al.[J].Chemical Communications,2010,46:3908-3910.
[7]	Boyer John-christopher;Cuccia Louis A;Capobianco John A .[J].Nano Letters,2007,7(03):847-852.
[8]	Nu(n)ez Nuria O;Quintanilla M;Cantelar E et al.[J].Journal of Nanoparticle Research,2010,12:2553-2565.
[9]	杨奉真,衣光舜,陈德朴,程京.纳米NaYF4：Yb,Ho上转换荧光粉的合成及其性质研究[J].高等学校化学学报,2004(09):1589-1592.
[10]	Yi Guangshun;Chow Ganmoog .[J].Journal of Materials Chemistry,2005,15:4460-4464.
[11]	Cao Tianye;Yang Tianshe;Gao Yuan et al.[J].Inorganic Chemistry Communications,2010,13:392-394.
[12]	Mahalingam V;Vetrone F;Naccache R.[J].Journal of Materials Chemistry,2009
[13]	Zhao Fei;Gao Song .[J].Journal of Materials Chemistry,2008,18:949-953.
[14]	Zhao Fei;Yuan Mei;Zhang Wen et al.[J].Journal of the American Chemical Society,2006,128:11758-11759.
[15]	徐利 .Yb<'3+>/Er<'3+>/Tm<'3+>/Ho<'3+>共掺氟氧化物玻璃光谱特性研究[D].长春理工大学,2010.
[16]	Wang XF;Mao SG;Bu YY;Yang XL;Ding JW .beta-Na(Y1.5Na0.5)F-6:Tm3+-A blue upconversion phosphor[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2009(3):325-327.
[17]	Pei XJ;Hou YB;Zhao SL;Xu Z;Teng F .Frequency upconversion of Tm3+ and Yb3+ codoped YLiF4 synthesized by hydrothermal method[J].Materials Chemistry and Physics,2005(2/3):270-274.
[18]	Chen G Y;Liu H C;Zhang Z G et al.[J].Journal of Physical Chemistry C,2008,112:12030-12036.
[19]	Wermuth M.;Gudel HU.;Riedener T. .Spectroscopy and upconversion mechanisms of CsCdBr3 : Dy3+[J].Physical Review.B.Condensed Matter,1998(8):4369-4376.
[20]	Fiorenzo Vetrone;John-Christopher Boyer;John A. Capobianco;Adolfo Speghini;Marco Bettinelli .Significance of Yb~(3+) concentration on the upconversion mechanisms in codoped Y_(2)O_(3):Er~(3+), Yb~(3+) nanocrystals[J].Journal of Applied Physics,2004(1):661-667.

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热解法制备KY3F10∶Yb3+、Tm3+纳米晶荧光标记材料

Synthesis of nanoparticles KY3F10 : Yb3+ ,Tm3+ fluorescence label material by pyrolysis

参考文献