从酚醛微球制备的角度总结了近年来国内外制备酚醛树脂闭孔中空微球的各种方法,包括喷雾干燥法、发泡法、悬浮聚合法以及微胶囊法等,并简要介绍了酚醛树脂微球的性能及应用研究,结合目前的研究与应用现状、差距和问题对该领域的发展趋势进行了展望.
Phenolic hollow microspheres have a set of outstanding characteristics such as low density, low thermal conductivity, good heat resistance, thermal abrasion, and high yield of carbon conversion. The recent development of fabrication methods of phenolic hollow microspheres is reviewed, including spray drying, foaming method, suspending polymerization and in-situ polymerization, and the performance and application research are reported in summary.The research tendency of these compounds is prospected.
参考文献
[1] | David S .Method for synthesizing thermo-expandable polymeric microspheres[P].US,6617364,2003-09-09. |
[2] | 李凯,杜中杰,张晨,励杭泉.中空酚醛微球的合成与表征[J].高分子材料科学与工程,2006(04):36-39. |
[3] | Erwin M.Wouterson;Freddy Y.C.Boey;Xiao Hu .Effect of fiber reinforcement on the tensile,fracture and thermal properties of syntactic foam[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(11):3183-3191. |
[4] | Wong SC.;Sui GX.;Yue CY.;Mai YW. .Characterization of microstructures and toughening behavior of fiber-containing toughened nylon 6,6[J].Journal of Materials Science,2002(13):2659-2667. |
[5] | Nair SV.;Goettler LA.;Wong SC. .FRACTURE RESISTANCE OF POLYBLENDS AND POLYBLEND MATRIX COMPOSITES .1. UNREINFORCED AND FIBRE-REINFORCED NYLON 6,6/ABS POLYBLENDS[J].Journal of Materials Science,1997(20):5335-5346. |
[6] | Wouterson E M;Boey F Y C et al.Specific properties and fracture toughness of syntactic foam:Effect of foam micro-structures[J].Composites Science and Technology,2005,65(11-12):1840. |
[7] | [OL].http://www.cqtech.com/why.html |
[8] | Nidia C. Gallego;James W. Klett .Carbon foams for thermal management[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(7):1461-1466. |
[9] | E. Bruneton;C. Tallarou;N. Gras-Naulin;A. Cosculluela .Evolution of the structure and mechanical behaviour of a carbon foam at very high temperatures[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(11):1919-1927. |
[10] | K.G.H.DESAI;H.J.PARK .Encapsulation of vitamin C in tripolyphosphate cross-linked chitosan microspheres by spray drying[J].Journal of Microencapsulation: Microcapsules Liposomes Nanoparticles Microcells Microspheres,2005(2):179-192. |
[11] | Zhou X W;Zhu Y F;Gong Q M et al.Preparation and properties of the powder SBR composites filled with CNTs by spray drying process[J].Materials Letters,2006,60(30):3769. |
[12] | Franklin V .Process of producing hollow particles and resulting product[P].US,2797201,1953-10-02. |
[13] | Reusova L A .Method of manufacturing hollow micro-spheres[P].Russian,2138521,1999-09-27. |
[14] | Reusova L A .Method for production of hollow microspheres in spray-drying plant[P].Russian,2178336,2002-01-20. |
[15] | 李凯 .热固性酚醛树脂中空微球的制备与表征[D].北京化工大学,2006. |
[16] | 成国祥,张立永,付聪.种子溶胀悬浮聚合法制备分子印迹聚合物微球[J].色谱,2002(02):102-107. |
[17] | Zhou H;Huang G S;Gao P et al.Preparation of porous/ hollow particles of phenolic resin[J].Polymers For Advanced Technologies,2007,18(07):582. |
[18] | Zhou H;Li B;Huang G S .Sound absorption behavior of multiporous hollow polymer micro-spheres[J].Materials Letters,2006,60(29):3451. |
[19] | Li K Z;Shi Z H;Li H J.Application of microcapsu-lation technology to the preparation of carbon foam[J].Science and Technology of Advanced Materials,2008(09):1. |
[20] | 石振海,李克智,李贺军,王闯,李照谦.闭孔碳微球泡沫材料制备工艺与性能研究[J].功能材料,2005(12):1944-1946,1950. |
[21] | 田卓,李克智,李贺军,石振海.碳泡沫导热性能及力学性能研究[J].无机材料学报,2008(06):1171-1174. |
[22] | 刘喜宗,李贺军,马托梅,王斌,李克智.原位聚合法制备酚醛树脂空心微球的工艺研究及性能表征[J].高分子学报,2009(07):695-699. |
[23] | 李鹏,刘德安,杨学忠.微球复合泡沫材料的研究和应用[J].玻璃钢/复合材料,2000(04):21-24. |
[24] | Gladysz GM;Perry B;Mceachen G;Lula J .Three-phase syntactic foams: structure-property relationships[J].Journal of Materials Science,2006(13):4085-4092. |
[25] | Shabde VS;Hoo KA;Gladysz GM .Experimental determination of the thermal conductivity of three-phase syntactic foams[J].Journal of Materials Science,2006(13):4061-4073. |
[26] | Grujicic M;Zhao CL;Biggers SB;Morgan DR .Experimental investigation and modeling of effective thermal conductivity and its temperature dependence in a carbon-based foam[J].Journal of Materials Science,2006(8):2309-2317. |
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