硅烷改性是目前钢筋混凝土结构上常用的防护手段之一。与普通涂料相比,硅烷具有较好的渗透性和疏水性。采用辛基三乙氧基硅烷对混凝土表面改性。通过接触角观察、吸水率测试、电化学测试以及傅立叶红外吸收测试得出:硅烷分子通过水解缩合反应在孔隙壁表面形成有机硅树脂;表面改性后的混凝土疏水效果明显,浸润角大于100°,混凝土吸水率显著降低,扩散阻抗明显增加,混凝土耐蚀性增强。
Silane modification is one of the common techniques used for enhancing the corrosion resistance of carbon steel in concrete, due to the superior penetrability and hydrophobicity of silane. Octyl triethoxysilane(OTES) was taken to modify the concrete surface. The results of IR spectra, contact angle, water absorption and electrochemical tests showed that a hydrophobic layer with water contact angle over 100°was formed on the micropore surface of concrete through the hydrolysis and condensation reactions of silane, resulting in a significant decrease of water absorption and enhancement of corrosion resistance of concrete.
参考文献
[1] | 胡融刚,黄若双,杜荣归,林昌健.氯离子侵蚀下钢筋在混凝土中腐蚀行为的EIS研究[J].物理化学学报,2003(01):46-50. |
[2] | 卢木.混凝土耐久性研究现状和研究方向[J].工业建筑,1997(05):1. |
[3] | 仲伟秋,贡金鑫.氯离子侵蚀环境下混凝土结构的耐久性评估[J].混凝土,2002(11):3-4. |
[4] | 黄君哲,周欲晓,王胜年,潘德强.海工混凝土结构表面涂层暴露试验及应用效果[J].中国港湾建设,2002(06):17-20,51. |
[5] | F. Tittarelli;G. Moriconi .The effect of silane-based hydrophobic admixture on corrosion of reinforcing steel in concrete[J].Cement and Concrete Research,2008(11):1354-1357. |
[6] | 陈珊,陈仁霖,陈学群,李国明.钢材表面硅烷处理后的防蚀性能[J].腐蚀与防护,2008(04):175-177,188. |
[7] | 张鹏,赵铁军,戴建国,郭平功,Wittmann F H.硅烷改性混凝土防水和抗氯离子性能试验研究[J].土木工程学报,2011(03):72-78. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%