采用水热法合成了氧化锌（ZHM）中空微米球，通过浸渍法得到负载罗丹明 B 酰肼（RHBH）的氧化锌微球（ZHM-RHBH），采用红外光谱（FT-IR）对其结构进行表征。将 ZHM-RHBH 掺杂到环氧树脂中，在 Q235碳钢基体上制备功能涂层，利用动电位极化曲线和电化学阻抗谱（EIS）考察了 ZHM-RHBH 对涂层缺陷处金属腐蚀的作用。结果表明，掺杂于涂层中的 ZHM-RHBH 不仅能够通过荧光响应指示涂层缺陷还可以抑制涂层缺陷处的腐蚀。
ZnO hollow microspheres (ZHM)were synthesized by hydrothermal method.The ZHM containing rhodamine B hydrazide (ZHM-RHBH)was obtained by loading RHBH to ZHM using impregnation method,and characterized by Fourier transform infrared spectroscopy (FT-IR).A functional coating was prepared on Q235 carbon steel substrate by adding ZnO-RHBH into the epoxy resin.The effect of ZHM-RHBH on metal corrosion at coating defects was studied by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS).It was found that the corrosion occurring at coating defects was inhibited by doping ZHM-RHBH into epoxy coating,and the ZHM-RHBH not only had certain healing effect for coating defects,but also could diagnose corrosion by fluorescence response.
参考文献
| [1] | 朱立;徐小连.彩色涂层钢板技术[M].北京:化学工业出版社,2005:10-15. |
| [2] | 曹楚南.悄悄进行的破坏-金属腐蚀[M].北京:清华大学出版社,2000:9-10. |
| [3] | 毛卫民.国产家电彩涂钢板分析[J].冶金丛刊,2000(05):11-12. |
| [4] | 王成晓,安德福.发展中的彩色涂层钢板生产[J].天津冶金,2004(06):38-39. |
| [5] | 马志军,潘圣广,程博.影响彩涂板 T 弯性能的原因分析与改进[J].科技风,2012(07):13-13. |
| [6] | 贺新,陈连生,俞俊杰,张静,孙力.表调/铬酸盐钝化复合膜对彩涂板性能的影响[J].河北理工大学学报(自然科学版),2007(03):41-44,48. |
| [7] | 范纯,张家琪,姜宝宇.彩涂板涂层附着力时效性能的研究[J].钢铁研究,2007(03):35-37. |
| [8] | 王雷,孙杰,安成强.粗糙度对彩色涂层与基体间附着力的影响[J].电镀与精饰,2010(05):41-43. |
| [9] | 王庆华,程斌.钝化镀锌板基板对彩涂板涂层附着力的影响研究[J].涂料工业,2011(10):67-70. |
| [10] | 宋玉苏,姚树人.涂层与基体金属附着力的研究进展[J].材料保护,1999(09):21-22. |
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