熔融碳酸盐燃料电池(MCFC)的NiO阴极在熔融碳酸盐中的溶解以及金属镍在电解质板中的沉积造成电池短路失效,严重阻碍了MCFC的商业化进程.综述了近年来MCFC的各种阴极材料在熔融碳酸盐中的溶解行为,并初步探讨了各种改性措施提高NiO在熔融碳酸盐中稳定性的机理.
参考文献
[1] | 林维明.燃料电池系统[M].北京:化学工业出版社,1996 |
[2] | 李乃朝;衣宝廉;张恩俊 等.不同工作条件下的熔盐燃料电池性能[J].电源技术,1997,21(03):110. |
[3] | Prabhu Ganesan;Hector Colon;Bala Haran et al.Study of cobalt-doped lithium nickel oxides as cathodes for MCFC[J].Journal of Power Sources,2002,111:109. |
[4] | Goirgi L;Carewska M;Patriarca M et al.Development and Characterization of novel cathode materials for Molten Car bonate Fuel Cell[J].Journal of Power Sources,1994,49:227. |
[5] | Nishima T;Uchida I;Selman J R .Gas Electrode Reactions in Molten Carbonate Media[J].Journal of the Electrochemical Society,1994,141:1191. |
[6] | Shigenori Mitsushima;Koichi Matsuzawa;Nobuyuki Kamiya;Ken-ichiro Ota .Improvement of MCFC cathode stability by additives[J].Electrochimica Acta,2002(22/23):3823-3830. |
[7] | Giorgi L;Carewska M;Scaccia S et al.[J].International Journal of Hydrogen Energy,1996,21:3313. |
[8] | Peelen W H A;Van Driel M;Hemmes K et al.A compara tive Study of NiO (Li),LiFeO2,and LiCoO2 Porous Cath odes for Molten Carbonate Fuel Cell[J].Journal of the Electrochemical Society,1994(141):3429. |
[9] | Doyon J D;Gilbert T;Davies G et al.NiO Solubility in Mixed Alkali/Alkaline Earth Carbonates[J].Journal of the Electrochemical Society,1987,134:3035. |
[10] | Molten Carbonate Fuel Cell Technology[A].,1990 |
[11] | Smith J L;Kucera G H;Brown A P.[A].Pennington,NJ,1990 |
[12] | Baumgartner C E;Arendt R H;Iacovangelo C D et al.Molten Carbonate Fuel Cell Cathode Materials Study[J].Journal of the Electrochemical Society,1984,131:2217. |
[13] | Veldhuis J B J;Eckes F C;Plomp L .The Dissolution Prop erties of LiCoO2 in Molten Li:KCarhonate[J].Journal of the Electrochemical Society,1992,139:L6. |
[14] | Bloom I.;Krumpelt M.;Smith J.L.;Lanagan M.T. .Development of LiFeO2-LiCoO2-NiO cathodes for molten carbonate fuel cells[J].Journal of the Electrochemical Society,1999(4):1336-1340. |
[15] | Hyung Joon Choi;Son Ki Ihm;Tae Hoon Lim et al.An e valuation of a stabilized NiO cathode for the reduction of NiO dissolution in MCFCs[J].Journal of Power Sources,1996,61:239. |
[16] | Escudero M J;Novoa X R;Rodrigo T et al.Influence of lanthanum oxide as quality promoter on cathodes for MCFC[J].Journal of Power Sources,2002,106:196. |
[17] | Daza L et al.Modified nickel oxides as cathode materials for MCFC[J].Journal of Power Sources,2000,86:329. |
[18] | Motohira N;Sensou T;Yamauchi K et al.Effect of Mg on the solubility of NiO in molten carbonate[J].Journal of Molecular Liquids,1999,83:95. |
[19] | Ota K.;Shibata S.;Yoshitake H.;Kamiya N.;Yamazaki N.;Takeishi Y. .SOLUBILITY OF COBALT OXIDE IN MOLTEN CARBONATE[J].Journal of the Electrochemical Society,1995(10):3322-3326. |
[20] | Lundblad A;Schwartz S;Bergman B .Effect of sintering procedures in development of LiCoO2-cathodes for the molten carbonate fuel cell[J].Journal of Power Sources,2000,90:224. |
[21] | Presented by Korea Institute of Science and Technology for Annex VI Meeting in Muchen,Germany 1998 under IEA Executive-Committee for Advanced Fuel Cell Program[M].,1998 |
[22] | Jonghee Han;Seung Goo Kim;Sung Pil Yoon et al.Perfor mance of LiCoO2-coated NiO cathode under pressured conditions[J].Journal of Power Sources,2002,106:153. |
[23] | SeunR Taek Kuk;Young Seck Song;Keon Kim .Properties of a new type of cathode for molten carbonate fuel cells[J].Journal of Power Sources,1999(1/2):50-56. |
[24] | Li Fei;Chen Hai yan;Wang Chun ming et al.A novel modified NiO cathode for molten carbonate fuel cells[J].Journal of Electroanalytical Chemistry,2002,531:53. |
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