利用磁控溅射法在不同基底偏压条件下制备了CrN/Si3N4纳米多层膜,分别用X射线衍射仪、原子力显微镜及纳米压痕仪表征多层膜的微观结构及力学性能,结果表明,衬底偏压对CrN/Si3N4纳米多层膜微观结构、界面结构、硬度和磨损性能有重要影响.漂浮电位时多层膜界面粗糙,CrN呈(200)、(111)共同生长,硬度和弹性模量低,有偏压且变化时界面宽度和粗糙度变化不大,硬度和模量变化的主要原因是不同衬底偏压下的晶格畸变导致两层材料弹性模量变化和晶粒尺寸变化.基底偏压的优化有助于改善涂层的屈服应力和断裂韧性.
参考文献
[1] | Veprek S;Niederhofer A;Moto K et al.Composition,nanostructure and origin of the ultrahardness in nc-TiN/aSi3N4/a-and nc-TiSi2 nanocomposites with Hv =80 to ≥105 GPa[J].Surface and Coatings Technology,2000,133-134:152. |
[2] | Veprek S;Veprek-Heijman MGJ;Karvankova P;Prochazka J .Different approaches to superhard coatings and nanocomposites[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1):1-29. |
[3] | Veprek S;Haussmann M;Reiprich S et al.Novel thermaldynamically stable and oxidation resistant superhard coating materials[J].Surface and Coatings Technology,1996,86-87:394. |
[4] | M. Nose;W. A. Chiou;M. Zhou;T. Mae;M. Meshii .Microstructure and mechanical properties of Zr-Si-N films prepared by rf-reactive sputtering[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,2002(3):823-828. |
[5] | Veprek S.;Reiprich S.;Haussmann M. .SUPERHARD NANOCRYSTALLINE W2N/AMORPHOUS SI3N4 COMPOSITE MATERIALS[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,1996(1):46-51. |
[6] | Shah H N;Jayaganthan R;Kaur D .Influence of silicon content on the microstructure and hardness of CrN coatings deposited by reactive magnetron sputtering[J].Materials Chemistry and Physics,2010,121(03):567. |
[7] | Mercs, D;Bonasso, N;Naamane, S;Bordes, JM;Coddet, C .Mechanical and tribological properties of Cr-N and Cr-SI-N coatings reactively sputter deposited[J].Surface & Coatings Technology,2005(1/4):403-407. |
[8] | Martinez E;Sanjines R;Karimi A;Esteve J;Levy F .Mechanical properties of nanocomposite and multilayered Cr-Si-N sputtered thin films[J].Surface & Coatings Technology,2004(0):570-574. |
[9] | Mercs D;Briois P;Demange V;Lamy S;Coddet C .Influence of the addition of silicon on the structure and properties of chromium nitride coatings deposited by reactive magnetron sputtering assisted by RF plasmas[J].Surface & Coatings Technology,2007(16/17):6970-6976. |
[10] | Lee JW;Chang YC .A study on the microstructures and mechanical properties of pulsed DC reactive magnetron sputtered Cr-Si-N nanocomposite coatings[J].Surface & Coatings Technology,2007(4/7):831-836. |
[11] | Lee, HY;Jung, WS;Han, JG;Seo, SM;Kim, JH;Bae, YH .The synthesis of CrSiN film deposited using magnetron sputtering system[J].Surface & Coatings Technology,2005(1/4):1026-1030. |
[12] | Benkahoul M;Robin P;Gujrathi SC;Martinu L;Klemberg-Sapieha JE .Microstructure and mechanical properties of Cr-Si-N coatings prepared by pulsed reactive dual magnetron sputtering[J].Surface & Coatings Technology,2008(16):3975-3980. |
[13] | Benkahoul, M;Robin, P;Martinu, L;Klemberg-Sapieha, JE .Tribological properties of duplex Cr-Si-N coatings on SS410 steel[J].Surface & Coatings Technology,2009(8):934-940. |
[14] | Bousser, E;Benkahoul, M;Martinu, L;Klemberg-Sapieha, JE .Effect of microstructure on the erosion resistance of Cr-Si-N coatings[J].Surface & Coatings Technology,2008(5/7):776-780. |
[15] | Hetal N. Shah;R. Jayaganthan;Avinash C. Pandey .Nanoindentation study of magnetron-sputtered CrN and CrSiN coatings[J].Materials & design,2011(5):2628-2634. |
[16] | Junhua Xu;Koichiro Hattori;Yutaka Seino .Microstructure and properties of CrN/Si_3N_4 nano-structured multilayer films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(2):239-245. |
[17] | Wainfan N;Parratt L G .X-ray reflection studies of the anneal and oxidation of some thin solid films[J].Journal of Applied Physics,1960,31(08):1331. |
[18] | Jankowski A F;Tsakalakos T .The effect of strain on the elastic constants of noble metals[J].Journal of Physics F:Metal Physics,1985,15(06):1279. |
[19] | Chen HY;Tsai CJ;Lu FH .The Young's modulus of chromium nitride films[J].Surface & Coatings Technology,2004(1):69-73. |
[20] | Tsui T Y;Pharr G M;Oliver W C.Nanoindentation and nanoscratching of hard carbon coating for magnetic disks[A].Boston,MA,1994 |
[21] | Pharr G M .Measurement of mechanical properties by ultralow load indentation[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,1998,253(1-2):151. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%