Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

材料科学技术（英文）, 2012, 28(5): 391-395.

Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

^1, , ^2,

1.Department of Chemistry, North Orissa University, Takatpur, Baripada 757003, India

2.Department of Chemistry, North Orissa University, Takatpur, Baripada 757003, India／Department of Chemistry, Veer Surendra Sai University of Technology, Burla, Sambalpur 768018, India

基金项目: Department of Atomic Energy, BRNS, Government of India forproviding financial support under Grant OM #2008/20/37/5/BRNS/1936

关键词：聚甲基丙烯酸甲酯 , 多壁碳纳米管 , 纳米复合材料 , 原位方法 , 制备 , 透氧 , 高分辨透射电子显微镜 , 扫描电子显微镜

Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

Ajaya K. Pradhan ^1, , Sarat K. Swain ^2,

1.Department of Chemistry, North Orissa University, Takatpur, Baripada 757003, India

2.Department of Chemistry, North Orissa University, Takatpur, Baripada 757003, India／Department of Chemistry, Veer Surendra Sai University of Technology, Burla, Sambalpur 768018, India

Keywords： Nanocomposites , Morphology , Permeability , Dispersion ,

Multiwalled carbon nanotubes （MWCNTs）/poly（methyl methacrylate）（PMMA） nanocomposites were prepared by ultrasonic assisted emulsifier free emulsion polymerization technique with variable concentration of functionalized carbon nanotubes. MWCNTs were functionalized with H 2 SO 4 and HNO 3 with continuing sonication and polished by H 2 O 2 . The appearance of Fourier transform infrared absorption bands in the PMMA/MWCNT nanocomposites showed that the functionalized MWCNT interacted chemically with PMMA macromolecules. The surface morphology of functionalized MWCNT and PMMA/MWCNT nanocomposites were studied by scanning electron microscopy. The dispersion of MWCNT in PMMA matrix was evidenced by high resolution transmission electron microscopy. The oxygen permeability of PMMA/MWCNT nanocomposites gradually decreased with increasing MWCNT concentrations.

参考文献

[1]	J. Sandler;M. S. P. Shaffer;T. Prasse;W. Bauhofer;K. Schulte;A. H. Windle .Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(21):5967-5971.
[2]	M. J. Biercuk;M. C. Llaguno;M. Radosavljevic;J. K. Hyun;A. T. Johnson;J. E. Fischer .Carbon nanotube composites for thermal management[J].Applied physics letters,2002(15):2767-2769.
[3]	M.Trujillo;M.L.Arnal;A.J.Muller .Thermal and Morphological Characterization of Nanocomposites Prepared by in-Situ Polymerization of High-Density Polyethylene on Carbon Nanotubes[J].Macromolecules,2007(17):6268-6276.
[4]	D. Qian;E. C. Dickey;R. Andrews .Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites[J].Applied physics letters,2000(20):2868-2870.
[5]	L. Jin;C. Bower;O. Zhou .Alignment of carbon nanotubes in a polymer matrix by mechanical stretching[J].Applied physics letters,1998(7/12):1197-1199.
[6]	C.Stephan;T.P.Nguyen .Characterization of singlewalled carbon nanotubes- PMMA composites[J].Synthetic Metals,2000(2):139-149.
[7]	C. Bower;R. Rosen;L. Jin;J. Han;O. Zhou .Deformation of carbon nanotubes in nanotube-polymer composites[J].Applied physics letters,1999(22):3317-3319.
[8]	J.N. Coleman;S. Curran .Physical doping of a conjugated polymer with carbon nanotubes[J].Synthetic Metals,1999(1/3):1174-1175.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

参考文献