利用高温高压釜,通过失重法、SEM、XRD以及电子探针微观结构分析等方法,研究了X60钢在不同高温条件下及2MPa分压的饱和CO2的环境介质中的腐蚀行为.结果表明:在90℃、120℃、150℃温度下,X60钢发生了严重的CO2腐蚀,表现出高的腐蚀速率,且腐蚀速率随着温度的升高呈先上升再下降的趋势,120℃时最大,表面腐蚀产物膜的主要成分为Fe3C和FeCO3.腐蚀过程显示局部腐蚀特征,为不同程度的点蚀和条状腐蚀.研究发现,Clˉ为点蚀的"激发剂",促进了点蚀的发生和发展.CO2腐蚀受温度、腐蚀产物膜、钢的显微组织、Clˉ等影响,是各种因素相互作用的结果.
参考文献
[1] | J. R. Shadley;S. A. Shirazi;E. Dayalan;E. F. Rybicki .Prediction of erosion-corrosion penetration rate in a carbon dioxide environment with sand[J].Corrosion: The Journal of Science and Engineering,1998(12):972-978. |
[2] | M. B. Kermani;A. Morshed .Carbon Dioxide Corrosion in Oil and Gas Production -- A Compendium[J].Corrosion: The Journal of Science and Engineering,2003(8):659-683. |
[3] | J.L.Crolet;M.R.Bonis .How to pressurize autoclaves for corrosion testing under carbon dioxide and hydrogen sulfide pressure[J].Corrosion: The Journal of Science and Engineering,2000(2):167-182. |
[4] | 周琦,徐鸿麟,周毅,刘斌.二氧化碳腐蚀研究进展[J].兰州理工大学学报,2004(06):30-34. |
[5] | Crolet J.L.;Thevenot N. .Role of conductive corrosion products on the protectiveness of corrosion layers[J].Revue de Metallurgie: Cahiers d'Informations Techniques,1996(2):269-280. |
[6] | B.Mishra .Development of a Predictive Model for Activation-Controlled Corrosion of Steel in Solutions Containing Carbon Dioxide[J].Corrosion: The Journal of Science and Engineering,1997(11):852-859. |
[7] | B. Kinsella;Y. J. Tan;S. Bailey .Electrochemical impedance spectroscopy and surface characterization techniques to study carbon dioxide corrosion product scales[J].Corrosion: The Journal of Science and Engineering,1998(10):835-842. |
[8] | Qi Zhou;Qin Ma;YuQiang Yi .H_2S/CO_2 Corrosion Behavior of Tubular Goods under High Temperature and High Pressure[J].Materials Science Forum,2006(0):370-373. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%