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研究了10%(质量分数,下同)间苯二酚双(二苯基磷酸酯)(RDP)阻燃聚碳酸酯(PC)/聚对苯二甲酸丁二醇酯(PBT)合金的增韧方法。5%苯乙烯-丁二烯-甲基丙烯酸酯(MBS)、3%乙烯-甲基丙烯酸丁酯-丙烯酸缩水甘油酯共聚物(PTW)复合增韧基体质量比70∶30的合金,缺口冲击强度达44.5 kJ/m2,拉伸强度达53.8 MPa,3.2 mm厚样条UL-94测试为V-0级。热重分析表明,RDP使上述合金第一失重段残炭率增加17.6%,700℃残炭率增加4.1%。聚苯醚(PPO)代替10%的合金基体后1.6 mm厚的样条阻燃等级达UL-94 V-1级,垂直燃烧残炭扫描电镜照片显示炭层表面结构致密。

The improvement in thoughness of polycarbonate(PC)/polybutylene terephthalate(PBT) alloy flame-retarded by10% bis(diphenyl phosphate)(RDP) was studied.with 5% styrene-butylene-methacrylate(MBS) and 3% ethylene-butylacrylate-glycidyl methacrylate(PTW) as toughener in PC/PBT alloy(mass ratio of 70∶30),the izod impact strength was 44.5 kJ/m2,tensile strength was 53.8 MPa and alloy(3.2mm thick) passed UL-94 V-0 test.Thermogravimetry analysis shows that residual mass of the alloy is 17.6% higher than that of the RDP-free one in the first mass-loss step,while 4.1% higher at 700 ℃.When 10% polyphenylene oxide(PPO) was employed in PC/PBT/RDP system,alloy specimens with 1.6 mm thickness passed UL-94 V-1 test.Scanning electron microscopy morphologies showed a dense residual char on the surface of vertically burned sample.

参考文献

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