非水体系快速挥发法直接合成有序介孔炭

新型炭材料, 2011, 26(4): 293-298.

非水体系快速挥发法直接合成有序介孔炭

李铁虎 ^1, , 王小宪 ^2, , 冀勇斌 ^3, , 金伟 ^4, , 林起浪 ^5,

1.西北工业大学材料学院,陕西西安710072;

2.西北工业大学材料学院,陕西西安710072;

3.西北工业大学材料学院,陕西西安710072;

4.西北工业大学材料学院,陕西西安710072;

5.福州大学材料学院,福建福州350002

关键词：多孔炭 , 非水体系 , 模板 , 炭化

Synthesis of ordered mesoporous carbons by non-aqueous solvent evaporation method

采用非水溶剂快速挥发法,以表面活性剂和酚醛树脂为结构导向剂和碳前驱体制备介孔炭.通过透射电镜、氮吸附-脱附和扫描电镜对产品的结构进行了表征.结果表明:所制介孔炭具有高度有序的二维六方结构.表面活性剂与酚醛树脂的配比对介孔炭的有序性有较大的影响,当其质量比高于1:0.25时,可保持良好的有序度.随着比值的减小,有序度逐渐降低.与蔗糖液相浸渍法相比,非水体系快速挥发法所制介孔炭具有较少的外微及大孔.

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非水体系快速挥发法直接合成有序介孔炭

Synthesis of ordered mesoporous carbons by non-aqueous solvent evaporation method

参考文献