研究了不同配比导电炭黑和羟乙基纤维素(HEC)感湿胶制备的碳湿敏元件的感湿特性,探讨了山梨醇增湿剂对感湿非线性特性的影响.对碳湿敏元件的体积电阻率、湿敏特性和复阻抗谱的测试结果表明,炭黑含量和山梨醇含量对非线性感湿特性有很大影响,2%炭黑试样在80%湿度附近开始出现电阻的非线性增大;适量山梨醇使试样的非线性湿度响应移向较低湿度区.试样的复阻抗谱在54%湿度时为1个带拖尾的半圆弧,80%湿度时变为带拖尾的2个半圆弧,更高湿度时是拖尾拉长变形明显的2个半圆弧,表明其等效电路是由包括体电阻、炭黑粒界电阻和电极接触电阻三个阻容并联体的串联组成.半圆弧数目随湿度增加的现象,与感湿膜中水分子增加使不同极化机制的作用变得更加明显有关.
参考文献
[1] | Huang J R,Li M Q,Huang Z Y,Liu J H.A novel conductive humidity sensor based on field ionization from carbon nanotubes[J].Sensors and Actuators A,2007,133(2):467-471. |
[2] | 徐文静,郭亚田,黄炳勋,顾善荣.GTS探空仪碳湿敏元件性能测试数据分析及相对湿度订正[J].气象科技,2007,35(3):423-428.Xu Wenjing,Guo Yatian,Huang Bingxun,Gu Shanrong.Analysis of GTS radiosonde humidity sensor testing data and correction of upper-air relative humidity radiosonde data[J].Meteorological Science and Technology,2007,35 (3):423-428. |
[3] | 洪利杰,杨慕杰,李杨.一种基于碳黑-聚四乙烯毗啶纳米复合物的新型湿度传感器[J].计测技术,2006,26(9):39-41.Hong Lijie,Yang Mujie,Li Yang.A novel humidity sensor based on carbon black/poly(4-vinyipyridine) nanocomposite[J].Metrology & Measurement Technology,2006,26(9):39-41. |
[4] | 陈文菊,郭淼,陈金霞,潘敏,陈裕泉.多壁碳纳米管湿敏传感器的研究[J].传感技术学报,2005,18(4):705-709.Chen Wenju,Guo Miao,Chen Jinxia,Pan Min,Chen Yuquan.Research into humidity sensors based on multi-wall carbon nanotubes[J].Journal of Transduction Technology,2005,18(4):705-709. |
[5] | Su Piguey,Huang Shuaychwen.Electrical and humidity sensing properties of carbon nanotubes-SiO2-poly (2-acrylamido-2-methylpropane sulfonate) composite material[J].Sensors and Actuators B,2006,113(1):142-149. |
[6] | Yu Haihu,Cao Tong,Zhou Lingde,Gu Erdan,Yu Dingshan,Jiang Desheng.Layer-by-layer assembly and humidity sensitive behavior of poly (ethyleneimine)/multiwall carbon nanotube composite films[J].Sensors and Actuators B,2006,119(2):512-515. |
[7] | Li Yang,Hong Lijie,Chen Yousi,Wang Huicai,Lu Xin,Yang Mujie.Poly(4-vinylpyridine)/carbon black composite as a humidity sensor[J].Sensors and Actuators B,2007,123(1):554-559. |
[8] | Shim Y B,Park J H.Humidity sensor using chemically synthesized poly(1,5-diaminonaphthalene) doped with carbon[J].J Electrochem Soc,2000,147(1):381-385. |
[9] | Yui H,Wu G Z,Sano H,Sumita M,Kino K.Morphology and electrical conductivity of injection-molded polypropylene/carbon black composites with addition of high-density polyethylene[J].Polymer,2006,47(10):3599-3608. |
[10] | 杨波,陈晓浪,陈光顺,郭少云.导电炭黑填充PP-EAA复合材料的形态及电性能[J].复合材料学报,2007,24(3):78-83.Yang Bo,Chen Xiaolang,Chen Guangshun,Guo Shaoyun.Morphology and conductivity of conductive carbon black filled PP-EAA composites[J].Acta Materiae Compositae Sinica,2007,24(3):78-83. |
[11] | 郑文杰,叶君,熊犍.改性羟乙基纤维素水溶液流变性能的研究进展[J].化工进展,2007,26(5):636-641.Zheng Wenjie,Ye Jun,Xiong Jian.Research progress of rheological behavior of modified hydroxyethyl cellulose solutions[J].Chemical Industry and Engineering Progress,2007,26(5):636-641. |
[12] | Jurgis Barkauskas,Investigation of conductometric humidity sensors[J].Talanta,1997,44(6):1107-1112. |
[13] | Barsoukov Evgenij,Macdonald J R.Impedance spectroscopy theory,experiment and applications[M].A John Wiley & Sons Ine,Publication,2005:240. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%