用简便的水热法制备出菱形、针状和树状的碳酸钙晶体,不需任何添加剂,也不需要对pH值进行控制.用XRD、SEM、FT-IR和TGA-DTA技术对产物的形貌、结构特征和热力学稳定性进行了表征.对实验条件的系统研究发现,通过控制反应物的浓度,即可简便地获得多种晶型和形貌的碳酸钙.
CaCO3 polymorphs with rhombohedra, needle-, tree-like morphologies have been synthesized by a convenient hydrothermal reaction with the absence of additives or elaborating pH control. XRD, SEM, FT-IR and TGA-DTA techniques were used to characterize the structural features and thermal behavior of the experimental products. The experimental conditions were explored systematically and it was found that polymorphs with manifold morphologies of CaCO3 could be conveniently synthesized by controlling the concentration of reactants.
参考文献
| [1] | Spanos N;Koutsoukos P G .[J].Journal of Physical Chemistry B,1998,102:6679. |
| [2] | Verdoes D;Kashchiev D;van Rosmalen G M .[J].Journal of Crystal Growth,1992,118:401. |
| [3] | Wang L;Sondi I;Matijivic E .[J].Journal of Colloid and Interface Science,1999,218:545. |
| [4] | Fukuhara M.;Takada J.;Kusano Y.;Fujii N. .Synthesis of tubes of a magnesium-rich carbonate and of its oxide decomposition products[J].Journal of the American Ceramic Society,1998(10):2746-2748. |
| [5] | Stupp S I;Braun P V .[J].Science,1997,277:1242. |
| [6] | Kuriyavar SI.;Hegde SG.;Ramaswamy AV.;Chakrabarty D. Mahapatra S.;Vetrivel R. .Insights into the formation of hydroxyl ions in calcium carbonate: temperature dependent FTIR and molecular modelling studies[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(8):1835-1840. |
| [7] | Hosoi K;Hashida T;Takahashi H et al.[J].Journal of Materials Science Letters,1997,16:382. |
| [8] | Ota Y;Inui S;Iwashita T et al.[J].Journal of the Ceramic Society of Japan,1996,104(03):196. |
| [9] | Gabrielli C.;Poindessous G.;Rosset R.;Maurin G. .Nucleation and growth of calcium carbonate by an electrochemical scaling process[J].Journal of Crystal Growth,1999(1/2):236-250. |
| [10] | Rodríguez-Clemente R;Gómez-Morales J .[J].Journal of Crystal Growth,1996,169:339. |
| [11] | Sims S D;Didymus J M;Mann S .[J].Journal of the Chemical Society,Chemical Communications,1995,45:1031. |
| [12] | Sugawara A;Kato T .[J].Journal of the Chemical Society,Chemical Communications,2000,216:487. |
| [13] | Wada N.;Umegaki T.;Yamashita K. .EFFECTS OF DIVALENT CATIONS UPON NUCLEATION, GROWTH AND TRANSFORMATION OF CALCIUM CARBONATE POLYMORPHS UNDER CONDITIONS OF DOUBLE DIFFUSION[J].Journal of Crystal Growth,1995(3):297-304. |
| [14] | Manoli F;Dalas E .[J].Journal of Crystal Growth,2000,218:359. |
| [15] | Walsh D;Mann S .[J].Nature,1995,377:320. |
| [16] | Li Q.;Shao MW.;Yu GH.;Wu J.;Li FQ.;Qian YT. .A solvent-reduction approach to tetrapod-like copper(I) chloride crystallites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(2):424-427. |
| [17] | Li Q.;Ding Y.;Li FQ.;Xie B.;Qian YT. .Solvothermal growth of vaterite in the presence of ethylene glycol, 1,2-propanediol and glycerin[J].Journal of Crystal Growth,2002(1/3):357-362. |
| [18] | Li Q;Shao M;Wu J et al.[J].Inorganic Chemistry Communications,2002,5:933. |
| [19] | Song K C;Kang Y .[J].Materials Letters,2000,42:283. |
| [20] | Manoli F.;Dalas E. .Calcium carbonate crystallization on xiphoid of the cuttlefish[J].Journal of Crystal Growth,2000(4):422-428. |
| [21] | Rajam S;Mann S .[J].Journal of the Chemical Society,Chemical Communications,1990,86(10):1789. |
| [22] | Saffo M B;Lowenstam H A .[J].Science,1978,200:1166. |
| [23] | Gómez-Morales J;Torrent-Burgués J;López-macípe A et al.[J].Journal of Crystal Growth,1996,166:1020. |
| [24] | Kanakis J;Dalas E .[J].Journal of Crystal Growth,2000,219:277. |
| [25] | Shaw W H R;Bordeaux J J .[J].Journal of the American Chemical Society,1955,77:4729. |
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