采用高温固相法制备了Sr0.96Al2O4:Eu0.02,Dy0.02,B0.08长余辉发光材料.利用XRD衍射仪、荧光分光光度计和热释光计量仪对样品进行了测试.对余辉衰减曲线的拟合表明,余辉曲线中的快衰减过程与V0(..)陷阱有关,而慢衰减过程源于Eu(.)Sr和Dy(.)Sr陷阱中的电子释放;随着球磨时间的增加,Dy(.)Sr陷阱浓度也随之增加.热释光光谱的曲线拟合表明,热释光峰反映的是Dy(.)Sr陷阱的特性;当陷阱浓度相差不大时,动力学级次越小,陷阱中电子的局域性越强,基质导带底产生一个由局域态组成的带尾,陷阱深度随之减小.
参考文献
[1] | Yamamoto H;Matsuzawa T .Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1997(0):287-289. |
[2] | Jia W;Yuan H;Holmstrom S et al.Photo-stimulated luminescence in SrAl2O4:Eu2 +,Dy3 + single crystal fibers[J].Journal of Luminescence,1999,83-84(01):469-465. |
[3] | Jianrong Qiu;K. Miura;H. Inouye;S. Fujiwara;T. Mitsuyu;K. Hirao .Blue emission induced in Eu~(2+)-doped glasses by an infrared femtosecond laser[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1999(2/3):185-188. |
[4] | 张天之,苏锵,王淑彬.MAl2O4:Eu2+、RE3+长余辉发光性质的研究[J].发光学报,1999(02):170-175. |
[5] | 胡劲,孙加林,刘建良,施安,徐茂,王开军.铝酸锶长余辉材料制备新工艺及发光机理[J].材料与冶金学报,2006(02):109-114. |
[6] | 吕兴栋,舒万艮.SrAl2O4:Eu2+,Dy3+晶格点缺陷的形成及其在发光材料中的作用[J].无机化学学报,2006(05):808-812. |
[7] | Yu-Lun Chang;Hsing-I. Hsiang;Ming-Tsai Liang .Characterization of strontium aluminate phosphors prepared from milled SrCO_3[J].CERAMICS INTERNATIONAL,2009(3):1027-1032. |
[8] | 张平 .花形铝酸锶系长余辉发光粉体合成新上艺及发光性能的研究[D].天津:天津大学,2006. |
[9] | P.D.Nsimama;O.M. Ntwaeaborwa;H.C.Swart .Auger electron/X-ray photoelectron and cathodoluminescent spectroscopic studies of pulsed laser ablated SrAl_2O_4:Eu~(2+),Dy~(3+) thin films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(2):512-517. |
[10] | MCKEEVER S W S.Thermoluminescence of Solids[M].Cambridge:Cambridge University Press,1983:5-7,66-74,48-49. |
[11] | 徐叙瑢;苏勉曾.发光学与发光材料[M].北京:化学工业出版社,2004:109-102. |
[12] | Bos, A.J.J.;Van Duijvenvoorde, R.M.;Van Der Kolk, E.;Drozdowski, W.;Dorenbos, P. .Thermoluminescence excitation spectroscopy: A versatile technique to study persistent luminescence phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2011(7):1465-1471. |
[13] | Katsumata T.;Toyomane S.;Tonegawa A.;Kanai Y.;Kaneyama U.;Shakuno K. Sakai R.;Komuro S.;Morikawa T. .Characterization of trap levels in long-duration phosphor crystals[J].Journal of Crystal Growth,2002(Pt.1):361-366. |
[14] | Ito S;Banno S;Suzuki K et al.Phase transitions in SrAl2O4[J].Zeitschrift für Physikalische Chemie,1977,105(S):173-178. |
[15] | 杨华明,李云龙,唐爱东,张向超,周灿伟.固相合成Co3O4纳米晶及晶化动力学研究[J].材料热处理学报,2005(04):1-4. |
[16] | Chang, CK;Li, W;Huang, XJ;Wang, ZY;Chen, X;Qian, X;Guo, R;Ding, YL;Mao, DL .Photoluminescence and afterglow behavior of Eu2+, Dy3+ and Eu3+, Dy3+ in Sr3Al2O6 matrix[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2010(3):347-350. |
[17] | Leiman V L .Monomolecular and bimolecular thermally stimulated luminescence of ionic crystals containing electron traps of a single type[J].Soviet Physics Solid State,1973,15:351-353. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%