采用溶剂热的方法合成了配合物[MnⅡ (PhCOO)4 (phen)2(Ac)2](1).通过X-射线单晶衍射、元素分析、X-射线粉末衍射和红外光谱的方法对其表征.其晶体属单斜晶系,P21/c空间群.晶胞参数:a=1.07699(15) nm,b=1.15416(16) nm,c=2.0360(3) nm,β=91.823(3)°,V=2.5295(6) nm3,Z=2,F=1154.配合物1为三核结构,通过π…π堆积作用形成了二维结构.配合物1的变温磁化率研究表明,金属锰离子在2～300 K温度区间显示反铁磁性耦合.CCDC:955788.
参考文献
| [1] | Yang EC.;Harden N.;Wernsdorfer W.;Zakharov L.;Brechin EK.;Rheingold AL.;Christou G.;Hendrickson DN. .Mn-4 single-molecule magnets with a planar diamond core and S=9[J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,2003(14/17):1857-1863. |
| [2] | Firestone KA;Reid P;Lawson R;Jang SH;Dalton LR .Advances in organic electro-optic materials and processing[J].Inorganica Chimica Acta,2004(13):3957-3966. |
| [3] | Tudor V.;Marin G.;Kravtsov V.;Simonov YA.;Lipkowski J.;Brezeanu M. Andruh M. .Alkoxo-bridged binuclear copper(II) complexes as nodes in constructing extended structures[J].Inorganica Chimica Acta,2003(0):35-42. |
| [4] | Gerard Ferey .Microporous Solids: From Organically Templated Inorganic Skeletons to Hybrid Frameworks...Ecumenism in Chemistry[J].Chemistry of Materials,2001(10):3084-3098. |
| [5] | Hagrman P.J.;Hagrman D.;Zubieta J. .Organic-Inorganic Hybrid Materials:From"Simple"Coordination Polymers to Organodiamine-Templated Molybdenum Oxides[J].Angewandte Chemie International Edition,1999(18):2638-2684. |
| [6] | A.K.Cheetham;G.Ferey;T.Loiseau .Open-framework inorganic materials[J].Angewandte Chemie International Edition,1999(22):3268-3292. |
| [7] | 张春丽,覃玲,杨清香,石智强,郑和根.4,4'-联苯咪唑及间苯二甲酸根二维锰（Ⅱ）配位聚合物的合成、结构及磁性[J].无机化学学报,2013(10):2157-2161. |
| [8] | Xiao-Ming Chen;Gao-Feng Liu .Double-Stranded Helices and Molecular Zippers Assembled from Single-Stranded Coordination Polymers Directed by Supramolecular Interactions[J].Chemistry: A European journal,2002(20):4811-4817. |
| [9] | 张美丽,张钢强,王记江,任宜霞,陈小利,吕磊.间苯二乙酸构筑的2D锰（Ⅱ）配合物的合成及晶体结构[J].无机化学学报,2013(04):671-676. |
| [10] | Xian-Ming Zhang;Ming-Liang Tong;Meng-Lian Gong;Xiao-Ming Chen .Supramolecular Organisation of Polymeric Coordination Chains into a Three-Dimensional Network with Nanosized Channels that Clathrate Large Organic Molecules[J].European journal of inorganic chemistry,2003(1):138-142. |
| [11] | Chen BL;Fronczek FR;Courtney BH;Zapata F .alpha-Po nets of copper(II)-trans-1,4-cyclohexanedicarboxylate frameworks based on a paddle-wheel building block and its enlarged dimer[J].Crystal growth & design,2006(4):825-828. |
| [12] | 刘春波,赵晗,王珊珊,查小林,李秀颖,车广波.以2,4＇-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴（Ⅱ）、锰（Ⅱ）配合物的水热合成及晶体结构[J].无机化学学报,2013(07):1533-1538. |
| [13] | 戚金丽,郑岳青,许伟.对甲醛苯甲酸构筑的Cu（Ⅱ）配合物：合成,结构及磁性质[J].无机化学学报,2013(11):2405-2414. |
| [14] | Hammond RP.;Haushalter RC.;Zubieta JA.;Cavaluzzi M. .Investigations of the copper bromide-2,2 '-dipyridyl system: Hydrothermal synthesis and structural characterization of molecular Cu3Br4(C10H8N2)(2), one-dimensional CuBr2(C10H8N2), and two-dimensional [Cu-2(OH)(2)(C10H8N2)(2)][Cu4Br6][J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1999(6):1288-1292. |
| [15] | Douglas J. Chesnut;Robert C. Haushalter;Jon Zubieta .The hydrothermal synthesis and structural characterization of a new class of compounds: nickel organoamine-halocadmates[J].Inorganica Chimica Acta,1999(1):41-51. |
| [16] | 于杰辉,施展,徐吉庆,崔小兵,丁红,荆维杰,储德清,华佳,徐家宁,王铁钢.Hydrothermal Synthesis and Characterization of a One-Dimensional Copper(Ⅰ) Halide Cluster with 1,10-Phenanthroline[J].中国化学(英文版),2002(06):560-563. |
| [17] | Yu JH.;Xu JQ.;Yang QX.;Pan LY.;Wang TG.;Lu CH.;Ma TH. .Hydrothermal synthesis, crystal structure and third-order non-linear optical property of a novel one-dimensional copper(I) cyanide-organodiimine coordination polymer [Cu-6(CN)(6)(phen)(4)](n) (phen=1,10-phenanthroline)[J].Journal of Molecular Structure,2003(1/2):1-7. |
| [18] | Xinxin Xu;Ying Ma;Enbo Wang .Synthesis,structure,and luminescent property of the first mixed-valence Cu-halide complex constructed from novel D6R Cu6Cl6 cores[J].Inorganic Chemistry Communications,2007(9):1113-1116. |
| [19] | Zhang LY;Zeng MH;Sun XZ;Shi Z;Feng SH;Chen XM .Crystal structure and magnetic properties of a helical ribbon polymer based on dimeric manganese(II) subunits[J].Journal of Molecular Structure,2004(1/3):181-184. |
| [20] | 徐敏,吕英杰,王东耀,董文.配位聚合物[NaMn（pic）3]n的水热合成和晶体结构[J].无机化学学报,2008(05):827-830. |
| [21] | 唐斯萍,张少华,杨颖群.2-苯甲酰苯甲酸铜配合物的合成、电化学、荧光及磁性研究[J].无机化学学报,2013(11):2465-2469. |
| [22] | Bing Liu;Ling Xu .A novel 3-D metal-organic framework constructed from a negative 2-D layer [Cu_2(BTB)_2]~(2-) and long linkers [Cu(4,4'-bipy)_2]~(2+):Synthesis,crystal structure and blue fluorescence[J].Inorganic Chemistry Communications,2006(4):364-366. |
| [23] | 新型链状化合物Mn3（dap）2（AsS3）2的溶剂热合成与表征[J].人工晶体学报,2012(06):1657-1663. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%