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Some recent results on the crystallization mechanism and structural characterization of nanostructures synthesized by completely crystallizing amorphous alloys are briefly reviewed. The morphologies, grain size, interfaces, defects, and nm-sized crystallites in the crystallized nanocrystalline samples are dealt with. Emphasis is placed on the features of interface structure and lattice structure of the nm-sized crystallites in these nanocrystalline materials.

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