欢迎登录材料期刊网

材料期刊网

高级检索

为了实现二氧化碳与环氧化合物共聚制备脂肪族聚碳酸酯过程中催化剂的循环利用,提高产物的热力学和力学性能,对其均相催化剂进行载化,即将活性组分/中心负载在无机或高分子载体上是一条有效的途径.文中综述了二氧化碳和环氧化合物共聚中负载型催化剂的研究进展,重点对羧酸锌催化体系、SalenMX催化体系、稀土三元催化体系等不同负载型催化剂的制备方法、催化效率、产物性能及优缺点进行了系统阐述,为负载型催化剂的进一步研究提供了参考.

参考文献

[1] Hongchun Li;Yongsheng Niu .Synthesis of biodegradable polycarbonate by alternating copolymerization of carbon dioxide and propylene oxide using a cobalt/Schiff base catalyst[J].Reactive & functional polymers,2011(2):121-125.
[2] Li, Z.;Qin, Y.;Zhao, X.;Wang, F.;Zhang, S.;Wang, X. .Synthesis and stabilization of high-molecular-weight poly(propylene carbonate) from ZnCo-based double metal cyanide catalyst[J].European Polymer Journal,2011(11):2152-2157.
[3] Darensbourg, D.J.;Yeung, A.D. .Thermodynamics of the carbon dioxide-epoxide copolymerization and kinetics of the metal-free degradation: A computational study[J].Macromolecules,2013(1):83-95.
[4] Wu, G.-P.;Wei, S.-H.;Ren, W.-M.;Lu, X.-B.;Xu, T.-Q.;Darensbourg, D.J. .Perfectly alternating copolymerization of CO_2 and epichlorohydrin using cobalt(III)-based catalyst systems[J].Journal of the American Chemical Society,2011(38):15191-15199.
[5] M. Ree;J. Y. Bae;J. H. Jung;T. J. Shin .A New Copolymerization Process Leading to Poly(propylene carbonate) with a Highly Enhanced Yield from Carbon Dioxide and Propylene Oxide[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(12):1863-1876.
[6] Duchateau R;van Meerendonkt WJ;Huijser S;Staal BBP;van Schilt MA;Gerritsen G;Meetsma A;Koning CE;Kemmere MF;Keurentjes JTF .Silica-grafted diethylzinc and a silsesquioxane-based zinc alkyl complex as catalysts for the alternating oxirane-carbon dioxide copolymerization[J].Organometallics,2007(17):4204-4211.
[7] Klaus, S.;Lehenmeier, M.W.;Herdtweck, E.;Deglmann, P.;Ott, A.K.;Rieger, B. .Mechanistic insights into heterogeneous zinc dicarboxylates and theoretical considerations for CO_2-epoxide copolymerization[J].Journal of the American Chemical Society,2011(33):13151-13161.
[8] Song PF;Xiao M;Du FG;Wang SJ;Gan LQ;Liu GQ;Meng YZ .Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride[J].Journal of Applied Polymer Science,2008(6):4121-4129.
[9] 贺虎,宋鹏飞,吴静姝,肖敏,王拴紧,孟跃中.高分子量二氧化碳-环氧丙烷共聚物的合成条件研究[J].高分子学报,2010(09):1148-1151.
[10] Wang JT;Zhu Q;Lu XL;Meng YZ .ZnGA-MMT catalyzed the copolymerization of carbon dioxide with propylene oxide[J].European Polymer Journal,2005(5):1108-1114.
[11] 黎演明,黄慨,杨辉,黄日波.MCM-41负载戊二酸锌催化剂催化C02和环氧丙烷的共聚反应[J].高分子材料科学与工程,2012(06):36-39,44.
[12] Alvaro M;Baleizao C;Das D;Carbonell E;Garcia H .CO2 fixation using recoverable chromium salen catalysts: use of ionic liquids as cosolvent or high-surface-area silicates as supports[J].Journal of Catalysis,2004(1):254-258.
[13] Alvaro M;Baleizao C;Carbonell E;El Ghoul M;Garcia H;Gigante B .Polymer-bound aluminium salen complex as reusable catalysts for CO2 insertion into epoxides[J].Tetrahedron,2005(51):12131-12139.
[14] 罗云飞,傅相锴,邹晓川,王长炜,胡小艳,贾紫永,张怀志.链接基团对固载手性Salen Mn(m)催化不对称环氧化反应的影响[J].无机化学学报,2011(07):1302-1308.
[15] 邹晓川,李俊,石开云,李贵节,傅相锴.有机-无机杂化载体-聚(苯乙烯-苯乙烯基膦酸)-磷酸氢锆-在烯烃环氧化反应中的应用[J].无机化学学报,2012(05):1031-1037.
[16] Gong BW;Fu XK;Chen JX;Li YD;Zou XB;Tu XB;Ding PP;Ma LP .Synthesis of a new type of immobilized chiral salen Mn(III) complex as effective catalysts for asymmetric epoxidation of unfunctionalized olefins[J].Journal of Catalysis,2009(1):9-17.
[17] Lu, H.;Qin, Y.;Wang, X.;Yang, X.;Zhang, S.;Wang, F. .Copolymerization of carbon dioxide and propylene oxide under inorganic oxide supported rare earth ternary catalyst[J].Journal of Polymer Science, Part A. Polymer Chemistry,2011(17):3797-3804.
[18] 路宏伟,秦玉升,王献红,赵晓江,王佛松.原位负载稀土三元催化剂催化环氧丙烷和二氧化碳的共聚合研究[J].高分子学报,2012(04):446-452.
[19] Yu KQ.;Jones CW. .Silica-immobilized zinc beta-diiminate catalysts for the copolymerization of epoxides and carbon dioxide[J].Organometallics,2003(13):2571-2580.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%