Curing of m-APII,a novel acetylene terminated polyisoimide based on asymmetrical biphenyldianhydride (a-BPDA),3,4'-diaminodiphenyl ether (3,4'-ODA) and 3-ethynylaniline endcap was characterized and its composites reinforced with G827 textiles were investigated.From DSC and DMA studies,it is found that m-APII is 250℃ curable with a free standing postcure at elevated temperatures which can give a higher Tg.The G827/m-APII laminates fabricated by compression molding displayed an excellent quality as evidenced by the C-scan and microscopic inspections.The mechanical test results showed that m-APII composites not only had good mechanical properties at room temperature but also exhibited an outstanding retention of properties at 300℃.
参考文献
[1] | WILSON D;STENZENBERGER H D;HERGENROTHER P M.Polyimides[M].New York.Chapman & Hall,1990 |
[2] | GHOSH M K;MITTAL K L.Polyimide.fundamentals and applications[M].New York:Narcel Dekker,Inc,1996 |
[3] | MEADOR MICHAEL A .Recent advances in the development of processable high-temperature polymers[J].Annual Review of Materials Science,1998,28:599-630. |
[4] | HUANG W X;WUNDER S L .FTIR investigation of cross-linking and Isomerization reactions of acetylene-terminated polyimide and polyisoimide oligomers[J].Journal of Polymer Science Part B:Polymer Physics,1994,32:2005-2017. |
[5] | BOTT R H;TAYLOR L T;WARD T C.Cross-linking and isomerization reactions of an acetylene terminated polyisoimide prepolymer[A].Washington,DC:American Chemical Society,1988:459-470. |
[6] | CHOW A W;HAMLIN R D;LANDIS A L et al.Structureproperty relations in processing high-performance polyisoimideimide resins[J].Journal of Rheology,1992,36(08):1651-1668. |
[7] | ZHUANG HONG .Synthesis and characterization of aryl phosphine oxide containing thermoplastics polyimides and thermosetting polyimides with controlled reactivity[D].Virginia:Virginia Polytechnic Institute and State University,1998. |
[8] | Gyu-Seok Song;Jun-Ho Lee;Seung-Boo Jung .Dynamic t-T_(dyn)-T_g diagram analysis of thermal isomerization of polyisoimide using complex electric modulus properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(11):3248-3255. |
[9] | Huang WX.;Wunder SL. .A DYNAMIC FT-IR METHOD FOR DETERMINING THE CURING TEMPERATURE RANGES OF AN ACETYLENE-TERMINATED POLYISOIMIDE PREPOLYMER[J].Journal of Applied Polymer Science,1996(3):511-520. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%