欢迎登录材料期刊网

材料期刊网

高级检索

静电纺射流在溶液浓度相对较大的情况下鞭动不稳定性较小,而且会以电势梯度最大方向为轴发生高速旋转,基于该基本原理,借助于常规平面铝板作为接收装置,获得了高度定向排列的微/纳米纤维集合体。为了将该定向排列微/纳米纤维束作为原丝通过预氧化和炭化处理制备微/纳米炭纤维,研究了湿热牵伸处理对定向排列微/纳米纤维结晶度和力学性能的影响。结果表明,平面铝板作为接收装置获得的定向排列微/纳米纤维束的结晶度和强度均较低,仅分别为22.66%和(0.58±0.014)cN/dtex,而经过4倍湿热牵伸,纤维束的结晶度和强度分别达到45.90%和(3.02±0.014)cN/dtex,性能得到了显著提高。

Our existing research showed that the electrospinning jet with a minor whipping instability for the solution with a relatively large concentration could rotate with a high speed around the direction of the maximum electric force gradient.Based on the principle,a conventional plane aluminum plate was successfully used as the collecting device to obtain highly-aligned micro-nano fiber assembly.For the purpose of its subsequent application in carbon micro-nano fibers through pre-oxidization and carbonization,this paper carried on a research on the influence of damp-heat drafting on crystallity and mechanical properties of deposited aligned fibers.Results show that aligned fibrous bundle obtained by using a plane aluminum plate as the collecting device has a low crystallity(22.66%) and strength((0.58±0.014) cN/dtex).However,after a fourfold damp-heat drafting,these values show a significant increase and are up to 45.90% and(3.02±0.014) cN/dtex,respectively.

参考文献

[1] Reneker DH.;Fong H.;Koombhongse S.;Yarin AL. .Bending instability of electrically charged liquid jets of polymer solutions in electrospinning[J].Journal of Applied Physics,2000(9 Pt.1):4531-4547.
[2] Zheng-Ming Huang;Y.-Z. Zhang;M. Kotaki .A review on polymer nanofibers by electrospinning and their applications in nanocomposites[J].Composites science and technology,2003(15):2223-2253.
[3] Dan Li;Yuliang Wang;Younan Xia .Electrospinning Nanofibers as Uniaxially Aligned Arrays and Layer-by-Layer Stacked Films[J].Advanced Materials,2004(4):361-366.
[4] Katta P;Alessandro M;Ramsier RD;Chase GG .Continuous electrospinning of aligned polymer nanofibers onto a wire drum collector[J].Nano letters,2004(11):2215-2218.
[5] Min Kyoon Shin;Sun I. Kim;Seon Jeong Kim .Controlled assembly of polymer nanofibers: From helical springs to fully extended[J].Applied physics letters,2006(22):223109-1-223109-3-0.
[6] Sun DH;Chang C;Li S;Lin LW .Near-field electrospinning[J].Nano letters,2006(4):839-842.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%