采用光学显微镜、扫描电镜及能谱分析术研究了复合添加微量Cr、Mn、Ti、Zr细化7A55合金铸锭组织的效果和机理.结果表明:复合添加0.04%Ti+0.17%Zr能在一定程度上细化7A55合金铸锭组织,复合添加0.20%Cr+0.20%Mn+0.03%Ti能够显著细化铸锭组织,其细化机理为含有Cr、Mn的原子团簇作为Al3Ti形核的基底促使α-Al成核;复合添加微量0.04%Cr+0.04%Mn+0.03%Ti+0.18%Zr产生了极强烈的晶粒细化效果,其细化机理为含有Cr、Mn的原子团簇作为Al3Ti、Al3Zr共同形核的基底使Al3(TixZr1-x)形核,Al3(TixZr1-x)使α-Al形核.随着Cr、Mn含量增加,铸锭晶粒向枝晶化、粗大化方向发展.
参考文献
[1] | Keams M A .The Mechanism of phase Transformations in crystalline solids[J].Light Metals,1996,59(17):713-720. |
[2] | Mohnanty P S;Gruzleski J E .Mechanism of grain refinement in aluminium[J].Acta Materialia,1995,43(05):2003-2011. |
[3] | Engdah T I;Hansen V;Warren et al.Investigation of fine precipitates in Al-Zn-Mg alloys after various heat treatments[J].Materials Science and Engineering A,2002,327:59-64. |
[4] | Stiller K;Warren P J;Hansen V et al.Investigation of precipitation in an Al-Zn-Mg alloy after two-step aging treatment at 100 ℃ and 150 ℃[J].Materials Science and Engineering A,1999,270:55-63. |
[5] | KMaloney S;Hono K;Polmcar I J .The chemistry of precipitates in an aged Al-2. 1Zn-1. 7Mg% alloy[J].Scripta Materialia,1999,41:1031-1038. |
[6] | Nesen E .precipitation of the metastable cubic Al3Zr phase in subperitectic Al-Zr alloy[J].Acta Materialia,1992,20(04):499-506. |
[7] | Vladivoj Ocenasek;Margarita Slamova .Resistance to recrystallization due to Sc and Zr addition to Al-Mg alloys[J].Materials Characterization,2001(2):157-162. |
[8] | Hansee L I V;Gjonnes J et al.Hrem study and structure modeling of the η,phase,the harding precipitates in commercial Al-Zn-Mg alloy[J].Acta Materialia,1999,47:2651-2659. |
[9] | Robson J D;Prangnell P B .Modelling Al3Zr dispersoid precipitation in multicomponent aluminum alloys[J].Materials and Engineering,2002,352:240. |
[10] | Stolzetc U K .The role of Cr and Mn to improve strength and stress corrosion resistance in Al-Zn-MgCu alloys[J].Transactions of the London Institute of Metals,1987,71(10):350-355. |
[11] | DorWard R C;Beernsen D J .Grain structure and quench-rate effects on strength and toughness of AA7050 Al-Zn-Mg-Cu-Zr alloy[J].Matallurgical Transaction A,1995,26(09):2481-2484. |
[12] | Spiva T;Trans S;Sriram S .Microstructure tensile deformation behaviour of aluminium alloy 7055[J].Journal of Materials Science,1997,32:2883-2894. |
[13] | Mohanty P S .Solidification technology in the foundry and casthouse[J].Acta Metallurgica Et Materialia,1995,43(05):2001-2012. |
[14] | Stolz U K;Terry B S.Phase equilibrium of aluminium-rich Al-Ti-B alloys-solubility of TiB2 in aluminium metals[J].Aluminium,1995(03):350-355. |
[15] | Kurz W;Fisher D J.Fundamentals of Solidification[M].Switzerland:Trans Tech Publication,1984:190-199. |
[16] | Greer A L;BunnA M .Modelling of inoculation of metallic metals:Application to grain refinement of aluminium by Al-Ti-B[J].Acta Materialia,2000,48:2823-2835. |
[17] | 秦究玉 .过渡元素合金化对铝合金组织结构的影响[D].济南:山东工业大学,1997. |
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