为了提高铝黄铜的耐蚀性能,采用次亚磷酸盐体系电镀Ni-P合金,从镀层沉积速度和外观角度,研究了镀液组成、pH值、电流密度、温度对镀层的影响,得出了最佳的工艺条件:40~60 g/L硫酸镍,8~10g/L氯化镍,8~12 g/L次亚磷酸钠,10~14 g/L柠檬酸,25~35g/L硼酸,pH值2.5~3.0,电流密度45~55 mA/cm2,温度58~70℃.采用本工艺得到的镀层均匀、光亮,耐蚀性优于铝黄铜.
参考文献
[1] | Sayed SM.;Ashour EA.;Youssef GI.;El-Raghy SM. .Effect of sulfide ions on the stress corrosion behaviour of Al-brass and Cu10Ni alloys in salt water[J].Journal of Materials Science,2002(11):2267-2272. |
[2] | Seungman Sohn;Tak Kang .The effects of tin and nickel on the corrosion behavior of 60Cu-40Zn alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):281-289. |
[3] | 王吉会;姜晓霞;李诗卓 .硼砷抑制黄铜脱锌的协同作用机制[J].科学通报,1997,42(06):669-672. |
[4] | Toivaneo R O;Lindroors U K.The effect of boron on the selective corrosion resistance of the Cu-35wt% Zn alloy[A].Toronto,Ottawa:National Research Council of Canada,1984:641-645. |
[5] | Picketing H W .Characteristic feactures of alloy polarization curves[J].Corrosion Science,1983,23(10):1107. |
[6] | 余维平;段淑珍 .电沉积Ni-P非晶态的初期结构形成机理[J].材料研究学报,1996,10(04):419-422. |
[7] | 冯力群 .镍磷合金电镀[P].中国,CN85104887A,1987-01-21. |
[8] | 饶厚曾,李国华,魏春哲,赵文海.钕铁硼永磁材料电镀Ni-P非晶态镀层[J].材料保护,2001(02):21-22. |
[9] | Morikawa T;Nakade T;Yokoi M et al.Electrodeposition of Ni-P alloys from Ni-citrate bath[J].Electrocheimica Acta,1997,42(01):115-118. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%