采用直接混合法简便地合成了纤维状聚苯胺纳米材料(PAni),其电导率达1.299S·cm。电化学阻抗谱表明,在3.5%NaCl溶液中,聚苯胺添加量为0.4%~0.6%时,涂覆聚苯胺/环氧复合涂层(P/E)的A3钢有很好的耐蚀作用,浸泡2400h后阻抗值仍大于10^9Ω·cm^2。
Polyaniline nanofibers (PAni) with high conductivity of 1. 299 S · cm were synthesized by rapid mixed method. The results of electrochemical impedance spectroscopy (EIS) showed that the polyaniline/epoxy (P/E) composite coating containing 0. 4% to 0. 6% PAni had good corrosion protection performance on A3 steel in NaCl (3.5%) solution. Impedance of the coating was more than 10^9 Ω · cm^2 after the electrode was immersed for 2400 h.
参考文献
[1] | Wessling B. .SCIENTIFIC AND COMMERCIAL BREAKTHROUGH FOR ORGANIC METALS[J].Synthetic Metals,1997(1/3):1313-1318. |
[2] | Schauer T.;Dulog L.;Eisenbach CD.;Joos A. .Protection of iron against corrosion with polyaniline primers [Review][J].Progress in Organic Coatings: An International Review Journal,1998(1):20-27. |
[3] | M. C. Bernard A. Hugot-Le Goff;S. Joiret;N. N. Dinh;N. N. Toan .Polyaniline layer for iron protection in sulfate medium[J].Journal of the Electrochemical Society,1999(3):995-998. |
[4] | Fahlman M.;Epstein AJ.;Jasty S. .CORROSION PROTECTION OF IRON/STEEL BY EMERALDINE BASE POLYANILINE - AN X-RAY PHOTOELECTRON SPECTROSCOPY STUDY[J].Synthetic Metals,1997(1/3):1323-1326. |
[5] | Santos JR.;Motheo AJ.;Mattoso LHC. .Investigation of corrosion protection of steel by polyaniline films[J].Electrochimica Acta,1998(3/4):309-313. |
[6] | Lu WK.;Wessling B.;Elsenbaumer RL. .CORROSION PROTECTION OF MILD STEEL BY COATINGS CONTAINING POLYANILINE[J].Synthetic Metals,1995(1/3):2163-2166. |
[7] | 张清华,王献红,景遐斌.聚苯胺复合膜的制备及性质[J].高分子材料科学与工程,2004(01):210-213. |
[8] | 高焕方,张胜涛,刘建平,刘超,彭超.聚苯胺防腐蚀涂料的研制及其性能[J].材料保护,2009(02):61-63. |
[9] | 景遐斌,王利祥,王献红,耿延候,王佛松.导电聚苯胺的合成、结构、性能和应用[J].高分子学报,2005(05):655-663. |
[10] | Wang CW.;Li MK.;Li HL.;Wang Z. .Well-aligned polyaniline nano-fibril array membrane and its field emission property[J].Chemical Physics Letters,2001(5-6):431-434. |
[11] | Kang ET.;Tan KL.;Neoh KG. .Polyaniline: A polymer with many interesting intrinsic redox states [Review][J].Progress in Polymer Science,1998(2):277-324. |
[12] | Jiaxing Huang;James A.Moore;J.Henry Acquaye;Richard B.Kaner .Mechanochemical Route to the Conducting Polymer Polyaniline[J].Macromolecules,2005(2):317-321. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%