贵金属,
2012, 33(z1): 24-27.
HE Xiaotang
1,
, WANG Huan
2,
, WU Xilong
3,
, LI Yong
4,
, ZHAO Yu
5,
, HAN Shouli
6,
, LI Kun
7,
, GUO Junmei
8,
1.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
2.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
3.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
4.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
5.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
6.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
7.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
8.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
基金项目:
the National High Technology Research and Development Program of China(863 Program)(2012AA063203;2012AA063204;2012AA063207)
Study on the Recovery of Rhodium from Spent Organic Rhodium Catalysts of Acetic Acid Industry Using Pyrometallurgical Process
HE Xiaotang
1,
, WANG Huan
2,
, WU Xilong
3,
, LI Yong
4,
, ZHAO Yu
5,
, HAN Shouli
6,
, LI Kun
7,
, GUO Junmei
8,
1.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
2.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
3.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
4.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
5.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
6.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
7.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
8.Sino-Platinum Metals Resources(Yimen)Co. Ltd., State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Sino-Platinum Metals Co. Ltd., Kunming, 650106,China
Keywords：
metallurgy
A new process recycling rhodium from organic waste containing rhodium in acetic acid industry is developed.Use the special affinity of base metal sulfides (FeS,Ni2S3,CuS,etc.) on platinum group metals,adopting high nickel matte trapping-aluminothermic activation method to recovery rhodium from incinerator residue of organic rhodium waste.The method is shorter process,lower equipment requirement,and the higher activity of rhodium black.In pyrometallurgy enrichment process,the recovery rate of rhodium reached 94.65％,the full flow of rhodium recovery rate was 92.04％.
参考文献
| [1] |
杜松,范怿涛,张俊杰.甲醇低压羰基合成醋酸的关键控制及其实现方法[J].现代化工,2010(02):78-80,82. |
| [2] |
黄宝华,王转玲.醋酸、醋酐的生产工艺[J].化学工程师,2008(10):29-32. |
| [3] |
王振宇,马晓迅,唐应吉.羰基合成醋酐联产醋酸的工业模试研究[J].现代化工,2009(09):68-69,71. |
| [4] |
Jing D .Production technologies and market analysis of acetic anhydride at home and abroad[J].Jiangsu Chemical Industry,2007,35:53-58. |
| [5] |
张蕾,曹彬,唐应吉,杨燕红,马晓迅.羰基合成醋酐联产醋酸工艺研究[J].化学工程,2010(05):91-94,97. |
| [6] |
Qiang D Q;Liu S J;Feng X L et al.A New Process for Concentration and Extraction of Precious Metals from Desulphurizing Cake by Hot Filtrating of Ni Anode Slime[J].Precious Metals,1996,17:56-59. |
| [7] |
Qian D Q;Liu S J .[P].China,CNl136595,1996. |
| [8] |
贺小塘.铑的提取与精炼技术进展[J].贵金属,2011(04):72-78. |
| [9] |
陈景.原子态与金属态贵金属化学稳定性的差异[J].中国有色金属学报,2001(02):288-293. |
| [10] |
贺小塘,刘伟平,吴喜龙,常桥稳,王欢,韩守礼.从有机废液中回收铱的工艺[J].贵金属,2010(02):6-9. |
