采用拉挤成型工艺制备碳纤维增强环氧树脂基复合材料,并对其进行人工加速紫外老化实验,对不同老化时间的试样进行弯曲强度测试、冲击强度测试、动态热机械分析(DMA)。结果表明,紫外老化仅影响到受紫外辐射的碳纤维环氧复合材料最外层,使对外层性能敏感的力学性能下降;紫外老化使复合材料玻璃化转变温度(Tg)提高,老化前期提高幅度相对较大,后期变化不明显;随着老化时间的增加,受到紫外辐射的最外层碳纤维/环氧树脂界面受到一定程度削弱。
Carbon fiber reinforced epoxy resin composite was made by pultrusion process, and then artificial accelerating UV aging test was taken. Bending strength test, impact strength test, dynamic mechanical thermal (DMA) analysis were applied to study the Influence of artificial accelerating UV aging on carbon fiber reinforced epoxy composite. The results show that the bending strength and the impact strength of carbon fiber reinforced epoxy composite decayed with UV aging time, especially as an exponential function because of the influence on the outermost layer of the composite ; glass transition temperature (Tg) increased relatively significant at the beginning of UV aging test, and then Tg showed no obvious change; within UV region, UV aging weaken the interface between carbon fiber and epoxy matrixto a certain extent, which gave reason to the decrease of the mechanical properties.
参考文献
[1] | Fitzer E;Gkogkidis A;Heine M .Carbon fibresand their composites(a review)[J].High Temperature and High Pressure,1984,16(04):363-392. |
[2] | Soutis C .Fibre reinforced composites in aircraft construc- tion[J].Progress in Aerospace Sciences,2005,41(02):143-151. |
[3] | A review of the present and future utilisation of FRP composites in the civil infrastructure with reference to their important in-service properties[J].Construction and Building Materials,2010(12):2419-2445. |
[4] | Park J M;Kong J W;Kim D S et al.Non-destructive damage sensing and cure monitoring of earhon fiher/ep- oxyaerylate composites with UV and thermal curing using electro-mieromechanical techniques[J].Composites Sci-ence and Technology,2004,64(16):2565-2575. |
[5] | Wypych G.Handbook of Material Weathering[M].北京:中国石化出版社,2004:37. |
[6] | Awaja, F;Pigram, PJ .Surface molecular characterisation of different epoxy resin composites subjected to UV accelerated degradation using XPS and ToF-SIMS[J].Polymer Degradation and Stability,2009(4):651-658. |
[7] | Hodgkinson J M.Mechanical testing of advanced fibre[M].北京:化学工业出版社,2005:104. |
[8] | Rosu L;Cascaval CN;Ciobanu C;Rosu D;Ion ED;Morosanu C;Enachescu M .Effect of UV radiation on the semi-interpenetrating polymer networks based on polyurethane and epoxy maleate of bisphenol A[J].Journal of Photochemistry and Photobiology, A. Chemistry,2005(2):177-185. |
[9] | Ricky S C W;Zhu Honggang;Christopher K Y L et al.Environmental degradation of epoxy-organoclaynanocom- posites due to UV exposure:part residual mechanical properties[J].Composites Science and Technology,2008,68(09):2149-2155. |
[10] | Ricky S.C. Woo;Yanghai Chen;Honggang Zhu .Environmental degradation of epoxy-organoclay nanocomposites due to UV exposure. Part I: Photo-degradation[J].Composites science and technology,2007(15/16):3448-3456. |
[11] | Jianwen Hu;Xiaogang Li;Jin Gao;Quanlin Zhao .Uv Aging Characterization Of Epoxy Varnish Coated Steel Upon Exposure To Artificial Weathering Environment[J].Materials & design,2009(5):1542-1547. |
[12] | Riesen R.Thermosets[M].Shanghai:Donghua Univer- sity Press,2009:133. |
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