可凝性气体分离如有机蒸气脱除与回收、气体脱湿等是近年来气体膜分离研究和应用的热点.与永久性气体相比,可凝性气体在聚合物膜中表现出一些”非常规”渗透行为.由于分子之间存在相互作用,聚合物膜中可凝性气体分子存在成簇迁移、聚合物溶胀和毛细管凝聚等现象.文中对这些渗透行为进行了总结和分析,并讨论了其对气体分离过程的影响.
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