采用高温高压釜实验研究了高硫高酸值原油温度对1Cr5Mo钢腐蚀速率的影响.利用扫描电镜和能谱技术观察并测试了腐蚀产物膜的微观形貌和产物膜的化学组成.利用电化学测试方法测试了带膜试样腐蚀电化学行为.结果表明,原油温度低于473 K时,1Cr5Mo钢主要腐蚀机理为环烷酸腐蚀,腐蚀速率增加缓慢;原油温度高于473 K时,1Cr5Mo钢主要腐蚀机理为环烷酸腐蚀、硫腐蚀,腐蚀速率迅速增加.当原油温度不大于513 K时,随原油温度增加,腐蚀产物膜渐趋完整,1Cr5Mo钢自腐蚀电流密度不断下降;当原油温度达到553 K时,产物膜变成疏松絮状结构,自腐蚀电流显著增加.
参考文献
[1] | E. Slavcheva;B. Shone;A. Turnbull .Review of naphthenic acid corrosion in oil refining[J].British Corrosion Journal,1999(2):125-131. |
[2] | G. C. Laredo;C. R. Lopez;R. E. Alvarez .Naphthenic acids, total acid number and sulfur content profile characterization in Isthmus and Maya crude oils[J].Fuel,2004(11/12):1689-1695. |
[3] | Omar Yepez .On the chemical reaction between carboxylic acids and iron, including the special case of naphthenic acid[J].Fuel,2007(7/8):1162-1168. |
[4] | A. Turnbull;E. Slavcheva;B. Shone .Factors controlling naphthenic acid corrosion[J].Corrosion: The Journal of Science and Engineering,1998(11):922-930. |
[5] | 徐志达,单石灵.加工含硫原油的设备腐蚀与对策[J].腐蚀科学与防护技术,2004(04):250-252. |
[6] | 苏芳云,朱文胜,杨志强,张伟.减压塔填料快速腐蚀失效原因分析[J].石油化工腐蚀与防护,2006(02):42-45. |
[7] | D.R. Qu;Y.G. Zheng;H.M. Jing;Z.M. Yao;W. Ke .High temperature naphthenic acid corrosion and sulphidic corrosion of Q235 and 5Cr1/2Mo steels in synthetic refining media[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2006(8):1960-1985. |
[8] | 张朝军,高玉青.辽河原油中环烷酸腐蚀动力学研究[J].大庆石油学院学报,1991(01):84. |
[9] | Adelina Borruto;Giovanni Narducci;Pietro Pietrosanti .Analysis of the cause of failure in 5Cr-1Mo pipes mounted in a preheating furnace[J].Frattura ed Integrità Strutturale,2012,20(02):22-31. |
[10] | 李子锋,田松柏,张雷,王子军.石油酸的腐蚀动力学[J].石油学报(石油加工),2009(06):826-829. |
[11] | Lorena Braga Moural;Rodrigo Freitas Guimar(a)esl;Hamilton Ferreira Gomes de Abreul et al.Naphthenic corrosion resistance,mechanical properties and microstructure evolution of experimental Cr-Mo steels with high Mo content[J].Materials Research,2012,15(02):277-284. |
[12] | 谷其发;李文戈.炼油厂设备腐蚀与防护图解[M].北京:中国石化出版社,2000 |
[13] | 郭昊,杜翠薇,李晓刚,陈云祥.X70钢在碳酸氢钠溶液中的腐蚀行为研究[J].装备环境工程,2007(03):40-44. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%