用高温熔融冷淬法制备Tm3+离子掺杂75TeO2-20ZnO-5La2O3碲酸盐玻璃,运用差示扫描量热仪(DSC)分析了玻璃样品的热稳定性,结果表明样品均具有良好的热稳定性.根据紫外-可见-近红外分光光度计测量得到的玻璃吸收光谱,运用Judd-Ofelt理论,计算了Tm3+离子在碲酸盐玻璃中的Judd-Ofelt强度参数、自发辐射概率A、荧光分支比β和辐射寿命ΤR等光谱参数.当掺杂浓度为0.8mol%时,玻璃热稳定性好,3H4的荧光寿命最长,为0.285ms,有望成为一种理想的S波段宽带光纤放大器用基质材料.
参考文献
[1] | Sandrine Hocde;Shibin Jiang;Xiang Peng;Nasser Peyghambarian;Tao Luo;Mike Morrell .Er~(3+) doped boro-tellurite glasses for 1.5 μm broadband amplification[J].Optical materials,2004(2):149-156. |
[2] | Kishi Y;Tanabe S .Properties of Tm3+-doped germanotellurite glasses for S-band amplifier[J].Journal of the American Ceramic Society,2006(1):236-240. |
[3] | Dacheng Zhou;Zhiguo Song;Guangwei Chi .NIR broadband luminescence and energy transfer in Er~(3+)-Tm~(3+)-co-doped tellurite glasses[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):881-884. |
[4] | H. Gebavi;D. Milanese;R. Balda;M. Ivanda;F. Auzel;J. Lousteau;J. Fernandez;M. Ferraris .Novel Tm~(3+)-doped fluorotellurite glasses with enhanced quantum efficiency[J].Optical materials,2011(3):428-437. |
[5] | Milanese, D.;Gebavi, H.;Lousteau, J.;Ferraris, M.;Schülzgen, A.;Li, L.;Peyghambarian, N.;Taccheo, S.;Auzel, F. .Tm~(3+) and Yb~(3+) co-doped tellurite glasses for short cavity optical fiber lasers: Fabrication and optical characterization[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2010(44/49):2378-2383. |
[6] | 陈炳炎,刘粤惠.掺铒0.7TeO2-0.2ZnO碲酸盐玻璃的热膨胀性能探讨[J].硅酸盐通报,2011(06):1395-1398. |
[7] | 陈炳炎,刘粤惠.掺铒0.7TeO2-0.2ZnO碲酸盐玻璃的热稳定性研究[J].硅酸盐通报,2011(04):977-981. |
[8] | Xu, R.;Tian, Y.;Hu, L.;Zhang, J. .2 μm spectroscopic investigation of Tm~(3+)-doped tellurite glass fiber[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2011(11/13):2489-2493. |
[9] | Zhou, D.;Wang, R.;Yang, Z.;Song, Z.;Yin, Z.;Qiu, J. .Spectroscopic properties of Tm~(3+) doped TeO_2-R _2O-La_2O_3 glasses for 1.47 μm optical amplifiers[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2011(11/13):2409-2412. |
[10] | 陈鹤,刘粤惠,周跃芬,戴世勋,姜中宏.掺铒碲酸盐玻璃的制备和光谱性能[J].硅酸盐学报,2004(02):166-170. |
[11] | Hrvoje Gebavi;Daniel Milanese;Guihua Liao;Qiuping Chen;Monica Ferraris;Mile Ivanda;Ozren Gamulin;Stefano Taccheo .Spectroscopic investigation and optical characterization of novel highly thulium doped tellurite glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2009(9):548-555. |
[12] | 陈鹤,刘粤惠,姚小旭,冯洲明.不同Tm3+浓度掺杂碲酸盐玻璃光谱性质研究[J].物理学报,2005(09):4427-4432. |
[13] | Nazabal V.;Todoroki S.;Nukui A.;Matsumoto T.;Suehara S.;Hondo T. Araki T.;Inoue S.;Rivero C.;Cardinal T. .Oxyfluoride tellurite glasses doped by erbium: thermal analysis, structural organization and spectral properties[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(1/3):85-102. |
[14] | 李科峰,汪国年,胡丽丽,张军杰,胡俊江.WO_3含量对Tm~(3+)掺杂TeO_2-WO_3-La_2O_3玻璃热学性能及光谱性质的影响[J].无机材料学报,2010(04):429-434. |
[15] | S. Tanabe .Optical transitions of rare earth ions for amplifiers: how the local structure works in glass[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1999(0):1-9. |
[16] | Kefeng Li;Qiang Zhang;Gongxun Bai;Sijun Fan;Junjie Zhang;Lili Hu .Energy transfer and 1.8μm emission in Tm~(3+)/Yb~(3+) codoped lanthanum tungsten tellurite glasses[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(2):573-578. |
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