综述了近年来环境友好阻燃PET的最新研究进展.分别从添加型和结构型两种阻燃剂进行阐述,其中添加型阻燃剂包括无机添加型阻燃剂(蒙脱土、金属氢氧化物、硼酸盐类以及多壁碳纳米管)和有机添加型阻燃剂(含磷的热致液晶、三磷腈派生物以及接枝阻燃基团的聚硅氧烷);结构型阻燃剂包括有机氧化膦类和次膦酸衍生物.并提出了未来阻燃聚酯的主要研究对象是共混阻燃聚酯的分散性和界面问题,从而提高阻燃PET的力学性能.
参考文献
| [1] | Lecomte, HA;Liggat, JJ .Commercial fire-retarded PET formulations - Relationship between thermal degradation behaviour and fire-retardant action[J].Polymer Degradation and Stability,2008(2):498-506. |
| [2] | Zhu, X.;Pan, Q.;Xu, H.;Lu, J. .Effects of coal and ammonium polyphosphate on thermal degradation and flame retardancy of polyethylene terephthalate[J].Journal of Polymer Research,2010(5):621-629. |
| [3] | Li J;Zhu H F;Li J et al.Thermal degradation behaviours of phos-phorusesilicon synergistic flame-retardant copolyester[J].Application of Polymer Science,2011,122(03):1993. |
| [4] | Liu, H.;Wang, R.;Xu, X. .Static and dynamic mechanical properties of flame-retardant copolyester/nano-ZnCO_3 Composites[J].Journal of Applied Polymer Science,2011(6):3131-3136. |
| [5] | Guo, W.Y.;Chuan, K.Y. .Crystallization, dispersion behavior and the induced properties through forming a controllable network in the crosslinked polyester-SiO_2 nanocomposites[J].Journal of Applied Polymer Science,2012(3):1773-1783. |
| [6] | Zhang, J.;Ji, Q.;Zhang, P.;Xia, Y.;Kong, Q. .Thermal stability and flame-retardancy mechanism of poly(ethylene terephthalate)/boehmite nanocomposites[J].Polymer Degradation and Stability,2010(7):1211-1218. |
| [7] | 方志勇.我国纺织品阻燃现状及发展趋势[J].染料与染色,2005(05):46-48,31. |
| [8] | 周政懋.我国阻燃技术发展新动向[J].阻燃材料与技术,2002(05):1. |
| [9] | 徐晓楠,韩海云.我国纺织品阻燃现状及发展趋势[J].消防技术与产品信息,2002(02):32-36. |
| [10] | 李宗剑 .不饱和聚酯/蒙脱土纳米复合材料阻燃性能及蒙脱土阻燃协效作用研究[D].河北工业大学,2007. |
| [11] | 蔡远征,郭正虹,方征平.稀土离子改性有机蒙脱土及其在PET阻燃中的应用[J].高分子材料科学与工程,2013(01):123-126. |
| [12] | Qin HL;Zhang SM;Zhao CG;Hu GJ;Yang MS .Flame retardant mechanism of polymer/clay nanocomposites based on polypropylene[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(19):8386-8395. |
| [13] | Liu, H.;Wang, R.;Xu, X. .Thermal stability and flame retardancy of PET/magnesium salt composites[J].Polymer Degradation and Stability,2010(9):1466-1470. |
| [14] | Berk Baltaci;Gaye O. Cakal;Goknur Bayram.Surfactant modified zinc borate synthesis and its effect on the properties of PET[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2013:38-44. |
| [15] | 刘培培 .碳纳米管对含磷阻燃聚酯的增强效应及其机理研究[D].北京服装学院,2009. |
| [16] | Wu, Z.;Xue, M.;Wang, H.;Tian, X.;Ding, X.;Zheng, K.;Cui, P. .Electrical and flame-retardant properties of carbon nanotube/poly(ethylene terephthalate) composites containing bisphenol A bis(diphenyl phosphate)[J].Polymer: The International Journal for the Science and Technology of Polymers,2013(13):3334-3340. |
| [17] | 张靖宗,纪全,夏延致,孔庆山.MWNTs/PET复合材料的阻燃性能[J].塑料,2009(04):1-3. |
| [18] | Chen Li;Bian Xiangcheng;Yang Rong et al.PET in situ composites improved both flame retardancy and mechanical properties by phosphorus-containing thermotropic liquid crystalline copolyester with aromatic ether moiety[J].Composites Science and Technology,2012,72:649. |
| [19] | Deng Y;Zhao CS;Wang YZ .Effects of phosphorus-containing thermotropic liquid crystal copolyester on pyrolysis of PET and its flame retardant mechanism[J].Polymer Degradation and Stability,2008(11):2066-2070. |
| [20] | 杜小华 .阻燃液晶共聚聚酯及其与PET共混物的性能研究[D].成都:四川大学,2004. |
| [21] | Zhang, X.;Zhong, Y.;Mao, Z.-P. .The flame retardancy and thermal stability properties of poly (ethylene terephthalate)/hexakis (4-nitrophenoxy) cyclotriphosphazene systems[J].Polymer Degradation and Stability,2012(8):1504-1510. |
| [22] | Zhang Xuan;Zhang Linping .The influence of synergistic effects of hexakis (4-nitrophenoxy)cyclotripbosphazene and POE-g-MA on anti-dripping and flame retardancy of PET[J].J Industr Eng Chem,2013,19:993. |
| [23] | Nizar Didane;Stéphane Giraud et al.A comparative study of POSS as synergists with zinc phosphinates for PET fire retardancy[J].Polymer Degradation and Stability,2012,97:383. |
| [24] | 周晓辉 .一种新型含磷硅阻燃剂的合成及在聚酯中的应用[D].北京服装学院,2009. |
| [25] | 于占昌.使用磷系阻燃剂的阻燃技术[J].世界橡胶工业,2004(07):6-10. |
| [26] | 黄金印;傅智敏 .双(对-羧苯基)苯基氧化膦阻燃改性聚酯的热解和燃烧特性实验研究[J].火灾科学,1999,8(04):50. |
| [27] | 张榕,朱新生,周舜华,濮江,路建美.涤纶阻燃技术研究进展[J].合成纤维,2006(08):9-12. |
| [28] | 魏雪梅,朱志国,刘培培,王锐,张大省.阻燃聚酯的研制及其结构和性能[J].纺织学报,2008(08):1-5. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%