研究了合金元素掺杂对TiV2.1Ni0.4系列合金的相结构及电化学性能的影响.XRD分析表明,该合金由V基固溶体主相和以网状分布于主相晶界的Ti2Ni第二相和C15型Laves第三相组成.BEI、EDS和电化学测试表明,Zr、Cu合金元素进入第二相晶格而使合金的电化学容量略降,但提高了合金的循环性能;Cr元素由于大部分进入到主相晶格而使合金的电化学循环性能大幅度提高,经40次循环后容量保持率仍达88.4%,但最大放电容量有所降低.
参考文献
[1] | Iwakura C.;Cboi W.K. .Electrochemical and Structural Characterization of Ti-V-Ni Hydrogen Storage Alloys With BCC Structure[J].Journal of the Electrochemical Society,2000(7):2503-2506. |
[2] | 代发帮,陈立新,刘剑,郑坊平,张志鸿,雷永泉.TiV2.1Nix(x=0.2~0.6)贮氢合金的相结构及电化学性能[J].稀有金属材料与工程,2005(09):1500-1504. |
[3] | Guo R;Chen L X;Lei Y Q et al.[J].Journal of Alloys and Compounds,2003,352:270. |
[4] | 陈立新;李露;王新华 et al.[J].Acta Physica Chimica Sinisa(物理化学学报),2006,22(05):523. |
[5] | 李露.A Study on the Novel V-Ti-Ni-Zr Based Dual-Phase Hydrogen Storage Electrode Alloys(新型V-Ti-Ni-Zr基双相贮氢电极合金研究)[M].杭州:浙江大学,2007 |
[6] | Qiao Yuqing;Zhao Minshou et al.[J].International Journal of Hydrogen Energy,2007,32:3427. |
[7] | Pan Hongge;Li Rui et al.[J].Journal of Alloys and Compounds,2008,463:189. |
[8] | Liu Yongfeng;Pan Hongge et al.[J].International Journal of Hydrogen Energy,2008,33:728. |
[9] | Miao He;Pan Hongge et al.[J].Journal of Power Sources,2008,184:627. |
[10] | 刘飞烨.Microstructure and Electrochemical Properties of V-Ti-Ni-Zr Based Hydrogen Storage Electrode Alloys(V-Ti-Ni-Zr基贮氢电极合金的微结构和电化学性能)[M].杭州:浙江大学,2008 |
[11] | Qiu Shujun;Sun Lixian;Xu Fen et al.[J].International Journal of Hydrogen Energy,2009,34:7246. |
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