采用分步溶液法,在碱性条件下合成出了3,5-二氯水杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元配合物,并培养出[Cu3L3(Phen)3].5H2O单晶(其中H2L=3,5-二氯水杨醛席夫碱缩异亮氨酸),其晶体结构经元素分析,红外光谱及X射线单晶衍射表征.
The 3,5-dichloro salicylaldehyde isoleucine phenanthroline copper(Ⅱ)ternary complex was composed in step-by-step method in alkaline solution,and the single crystal[Cu3L3(Phen)3].5H2O(H2L=2-[(3,5-Dichloro-2-hydroxy-benzylidene)-amino]-3-methyl-pentanoic acid)was determined from the ternary complex.The structure of the single crystal has been characterized by elemental analysis,IR and X-ray single crystal diffraction.
参考文献
| [1] | Kureshy R I;Khan N H .Mononuclear Chiral Ruthenium(Ⅱ)Schiff base Complexes,Synthesis,Physicochemical Studies and Reactivity with π-Acceptor Ligands[J].Polyhedron,1993,12(02):195-201. |
| [2] | Paredes-Garcia V;Venegas-Yazigi D;Latorre RO;Spodine E .Electronic properties of mixed valence iron(II,III) dinuclear complexes with carboxylate bridges[J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,2006(9):2026-2032. |
| [3] | Michele Gullotti;Laura Santagostini;Roberto Pagliarin;Alessandro Granata;Luigi Casella .Synthesis and characterization of new chiral octadentate nitrogen ligands and related copper(II) complexes as catalysts for stereoselective oxidation of catechols[J].Journal of molecular catalysis, A. Chemical,2005(1/2):271-284. |
| [4] | Ando R.;Inden H.;Sugino M.;Ono H.;Sakaeda D.;Yagyu T.;Maeda M. .Spectroscopic characterization of amino acid and amino acid ester-Schiff-base complexes of oxovanadium and their catalysis in sulfide oxidation[J].Inorganica Chimica Acta,2004(5):1337-1344. |
| [5] | Sheldrick G M.SHELXS97 and SHELXL97[M].University of Goettingen,Germany,1997 |
| [6] | Legon A.C. .Prereactive Complexes of Dihalogens XY with Lewis Bases B in the Gas Phase: A Systematic Case for the Halogen Analogue B...XY of the Hydrogen Bond B...HX[J].Angewandte Chemie International Edition,1999(18):2686-2714. |
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