采用熔融共混制备了聚乳酸/碳纳米管复合材料(PLA/CNTs).利用透射电镜(TEM)、差示扫描量热仪(DSC)和热重分析仪(TGA)对复合体系的形态、冷结晶行为以及热稳定性进行了研究.结果表明,羧基化的碳纳米管均匀分散于聚乳酸基体中形成了纳米复合材料;PLA/CNTs复合体系不从熔体冷却结晶,但可以在较慢的升温过程中固态下冷结晶,CNTs的存在一定程度上阻碍了PLA基体的冷结晶;此外,复合体系的热稳定性与纯聚乳酸相比有所提高.
参考文献
[1] | Potschke P.;Fornes TD.;Paul DR. .Rheological behavior of multiwalled carbon nanotube/polycarbonate composites[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(11):3247-3255. |
[2] | Wu DF;Wu L;Zhang M .Rheology of multi-walled carbon nanotube/poly(butylene terephthalate) composites[J].Journal of Polymer Science, Part B. Polymer Physics,2007(16):2239-2251. |
[3] | Wu DF;Wu L;Wu LF;Xu B;Zhang YS;Zhang M .Nonisothermal cold crystallization behavior and kinetics of polylactide/clay nanocomposites[J].Journal of Polymer Science, Part B. Polymer Physics,2007(9):1100-1113. |
[4] | 吴亮,吴德峰,吴兰峰,张明.聚乳酸/蒙脱土纳米复合材料的冷结晶及熔融行为[J].高分子材料科学与工程,2007(05):124-127. |
[5] | Gorrasi G;Sarno M;Di Bartolomeo A;Sannino D;Ciambelli P;Vittoria V .Incorporation of carbon nanotubes into polyethylene by high energy ball milling: Morphology and physical properties[J].Journal of Polymer Science, Part B. Polymer Physics,2007(5):597-606. |
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