Skutterudite热电材料的最新研究进展

材料导报, 2007, 21(1): 37-45.

Skutterudite热电材料的最新研究进展

胡安徽 ^1, , 杨君友 ^2, , 鲍思前 ^3, , 樊希安 ^4, , 段兴凯 ^5,

1.华中科技大学模具技术国家重点实验室,武汉,430074

2.华中科技大学模具技术国家重点实验室,武汉,430074

3.华中科技大学模具技术国家重点实验室,武汉,430074

4.华中科技大学模具技术国家重点实验室,武汉,430074

5.华中科技大学模具技术国家重点实验室,武汉,430074

基金项目: 国家重点基础研究发展计划(973计划)(2004CCA03200) 国家自然科学基金(50401008)

关键词：方钴矿 , 热电材料 , 填充限度 , 低维

Recent Development of Skutterudite Thermoelectric Material

首先介绍了填充式Skutterudite热电材料在成分优化方面的研究进展,再从组织结构优化以及合成低维Skutterudite材料等几个方面探讨了近年来Skutterudite类热电材料的研究状况和最新进展.

参考文献

[1]	Sales BC.;Chakoumakos BC.;Keppens V.;Thompson JR.;Mandrus D. .FILLED SKUTTERUDITE ANTIMONIDES - ELECTRON CRYSTALS AND PHONON GLASSES[J].Physical Review.B.Condensed Matter,1997(23):15081-15089.
[2]	Sales B C;Mandrus D;Williams R K .Filled skutterudite antimonides:A new class of thermoelectric materials[J].Science,1996,272(5266):1325.
[3]	Nolas GS.;Slack GA.;Cohn JL. .Effect of partial void filling on the lattice thermal conductivity of skudderudites[J].Physical Review.B.Condensed Matter,1998(1):164-170.
[4]	Shi X;Zhang W;Chen LD;Yang J .Filling fraction limit for intrinsic voids in crystals: Doping in skutterudites[J].Physical review letters,2005(18):5503-1-5503-4-0.
[5]	Chen L D;Tang X F;Kawahara T.Multi-filling approach for the improvement of thermoelectric properties of skutterudites[A].,2001:57.
[6]	Rowe D M;Kuznetsov V L;Kuznetsova L A.Thermoelectric properties of the Ce1-x LnxFe4Sb12 (Ln= rare earth)skutterudites[A].,1998:323.
[7]	Berardan D;Godart C;Alleno E et al.Chemical properties and thermopower of the new series of skutterudite Ce1-pUbpFe4Sb12[J].Journal of Alloys and Compounds,2003,351:18.
[8]	Giri R;Uanase N;Sekine C.La doping effect in thermoelectric properties of skutterudite compound CeRu4P12[A].,2002:60.
[9]	Chakoumakos B C;Sales B C;Mandrus D G et al.Structure disorder and thermal conductivity of the semiconducting clathrate Sr8Ga16Ge30[J].Journal of Alloys and Compounds,2000,296:80.
[10]	Tang X F;Chen L D;Zhang L M et al.High-temperature thermoelectric properties of n-type Bay Nix Co4-x Sb12[J].Journal of Materials Research,2001,16:3343.
[11]	Slack G A et al.Some properties of semiconducting IrSb3[J].Journal of Applied Physics,1994,76:1665.
[12]	Borshchevsky A;Fleurial J P;Allevato E et al.[J].American Institute of Physics Conf Proc,1995,316:3.
[13]	Caillat T.;Fleurial JP.;Borshchevsky A. .PROPERTIES OF SINGLE CRYSTALLINE SEMICONDUCTING COSB3[J].Journal of Applied Physics,1996(8):4442-4449.
[14]	Nakagawa H;Tanaka H;Kasama A.Grain size effects on thermoelectric properties of hot-pressed CoSb[A].,1997:351.
[15]	Bertini L.Grain size dependence of transport properties of nano-engineered thermoelectric CoSb3[A].,2003:93.
[16]	Christian Stiewe;Luca Bertini;Muhammet Toprak .Nanostructured Co_(1-x)Ni_x(Sb_(1-y)Te_y)_3 skutterudites:Theoretical modeling,synthesis and thermoelectric properties[J].Journal of Applied Physics,2005(4):043317-1-7-0.
[17]	Yang L;Wu J S;Zhang L T .Thermoelectric properties of some skutterudite compounds with different grain size[J].Journal of Alloys and Compounds,2004,375:114.
[18]	Mi J L;Zhao X B;Zhu T J et al.Solvothermal synthesis of nanostructured ternary skutterudite Fe0.5 Ni0.5 Sb3[J].Journal of Alloys and Compounds,2005,399:260.
[19]	Watcharapasorn A .Influence of cation and anion substitutions on the thermoelectric properties of pnictide skutterudite compounds[J].Dissertation Abstracts Int,2003,64(03):1446.
[20]	杨磊,张澜庭,吴建生.致密度对填充skutterudite化合物La0.75Fe3CoSb12热电性能的影响[J].物理学报,2004(02):537-542.
[21]	Arnache O;Girata D;Perez F;Castro LF;Prieto P;Lopera W .Electrical and structural properties of Ce0.9CoFe3Sb12 thermoelectric thin films[J].Solid State Communications,2005(5):343-346.
[22]	Anno H.Preparation and thermoelectric properties of CoSb3 thin films on GaAs(100) substrate[A].,1997:338.
[23]	V. Savchuk;A. Boulouz;S. Chakraborty;J. Schumann;H. Vinzelberg .Transport and structural properties of binary skutterudite CoSb_(3) thin films grown by dc magnetron sputtering technique[J].Journal of Applied Physics,2002(9):5319-5326.
[24]	Liu H et al.Nano-dendrites in NaFe4 P12 nano-wires synthesized by hydrothermal method[J].Optical Materials,2003,23:475.
[25]	Liu H;Wang J Y;Hua X B et al.Preparation of filled skutterudite nanowire by a hydrothermal method[J].Journal of Alloys and Compounds,2002,334:313.
[26]	Joshua R. Williams;Arwyn L. E. Smalley;Heike Sellinschegg;Carrie Daniels-Hafer;Jennifer Harris;Mark B. Johnson;David C. Johnson .Synthesis of Crystalline Skutterudite Superlattices Using the Modulated Elemental Reactant Method[J].Journal of the American Chemical Society,2003(34):10335-10341.
[27]	Rama Venkatasubramanian et al.Thin-film thermoelectric devices with high room-temperature figures of merit[J].NATURE,2001,413:597.
[28]	Williams JR.;Johnson DC. .Synthesis of the new metastable skutterudite compound NiSb3 from modulated elemental reactants[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2002(16):4127-4130.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Skutterudite热电材料的最新研究进展

Recent Development of Skutterudite Thermoelectric Material

参考文献