0.15mol/L TiCl3的饱和NaCl水溶液加添加剂尿素(尿素/Ti3+摩尔比为1:10)用水热法170℃下反应4h在玻璃基板上制备了TiO2纳米材料(粉末和薄膜),SEM和XRD技术表征结果说明,生成的TiO2为板钛矿型晶体,TiO2粉末是由TiO2纳米棒自组装成的微米球,薄膜则是大面积纳米棒阵列形成.探索了制备TiO2纳米材料的最优条件,并讨论了反应机理.
参考文献
| [1] | Song C X;Wang D B;Gu G H et al.[J].Journal of Colloid and Interface Science,2004,272:340-344. |
| [2] | Chen K Y;Chen Y W .[J].Powder Technology,2004,141:69-74. |
| [3] | Blesic M D;Saponjic Z V;Nedeljkovic J M et al.[J].Materials Letters,2002,54:298-302. |
| [4] | Zhang J;Wang B J;Ju X et al.[J].Polymer,2001,42:3697-3702. |
| [5] | Gundiah G;Rao C N R .[J].Solid State Sciences,2000,2:877-882. |
| [6] | Holgado M.;Ibisate M.;Serna CJ.;Lopez C.;Meseguer F.;Cintas A. .Three-dimensional arrays formed by monodisperse TiO2 coated on SiO2 spheres[J].Journal of Colloid and Interface Science,2000(1):6-11. |
| [7] | Maira A.J.;Yeung K.L.;Lee C.Y.;Yue P.L. .Size Effects in Gas-Phase Photo-oxidation of Trichloroethylene Using Nanometer-Sized TiO_2 Catalysts[J].Journal of Catalysis,2000(1):185-196. |
| [8] | Huisman CL;Schoonman J;Goossens A .The application of inverse titania opals in nanostructured solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(1):115-124. |
| [9] | Yanfeng Gao;Yoshitake Masuda;Kunihito Kumoto .Micropatterning of TiO_2 Thin Film in an Aqueous Peroxotitanate Solution[J].Chemistry of Materials,2004(6):1062-1067. |
| [10] | Jia Hong Pan;Wan In Lee .Preparation of Highly Ordered Cubic Mesoporous WO_3/TiO_2 Films and Their Photocatalytic Properties[J].Chemistry of Materials,2006(3):847-853. |
| [11] | Motonari Adachi;Yusuke Murata;Jinting Jiu;Jun Takao .Highly Efficient Dye-Sensitized Solar Cells with a Titania Thin-Film Electrode Composed of a Network Structure of Single-Crystal-like TiO_2 Nanowires Made by the "Oriented Attachment" Mechanism[J].Journal of the American Chemical Society,2004(45):14943-14949. |
| [12] | Liu K;Fu H;Shi K et al.[J].Journal of Physical Chemistry B,2005,109(40):18719-18722. |
| [13] | Mane R S;Lee W J;Pathan H M et al.[J].Journal of Physical Chemistry B,2005,109(51):24254-24259. |
| [14] | Francisco Gracia;Juan P.Holgado;Agustin R.Gonzalez-Elipe .Photoefficiency and Optical,Microstructural,and Structural Properties of TiO_2 Thin Films Used as Photoanodes[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(5):1688-1697. |
| [15] | Ho WK;Yu JC;Yu JG .Photocatalytic TiO2/glass nanoflake array films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(8):3486-3492. |
| [16] | Yang S W;Gao L .[J].Chemistry Letters,2005,34(07):1044-1045. |
| [17] | Eiji Hosono;Shinobu Fujihara;Keita Kakiuchi;Hiroaki Imai .Growth of Submicrometer-Scale Rectangular Parallelepiped Rutile TiO_2 Films in Aqueous TiCI_3 Solutions under Hydrothermal Conditions[J].Journal of the American Chemical Society,2004(25):7790-7791. |
| [18] | Niesen T P;de Guire M D .[J].Journal of Electroceramics,2001,6(03):169-207. |
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