采用溶胶-凝胶法制备特定溶胶pH值的催化剂前躯体,并分别采用马弗炉和管式炉两种不同焙烧方法制备了La07Sr0.3 Mn1-xFexO3(x=0,0.2)系列样品.发现Fe元素的加入使钙钛矿团聚程度增加、比表面积下降、样品中SrCO3的生成量减少使用管式炉焙烧的La07Sr0.3 Mn0.8 Fe0.2O3样品,形成的颗粒均匀,直径在40~ 80nm左右,拥有最大的比表面积(19.7 m2·g-1)、较完整钙钛矿物相结构,具有较好的NOx储存性能和氧化性能.
参考文献
[1] | 王志成,付名利,吴军良,黄碧纯,梁红,叶代启.NO对LaMnO3与La0.8K0.2MnO3催化氧化碳烟活性影响[J].中国稀土学报,2012(03):289-294. |
[2] | 赵秋伶,徐小健,蔡秀琴.汽车尾气净化催化剂及载体的研究进展[J].广州化工,2009(08):15-18. |
[3] | 赵震,杨向光,吴越.稀土-碱土-过渡金属类钙钛石(A2BO4)复合氧化物催化剂的固态物化性质及对Nox 消除反应的催化性能[J].中国稀土学报,2003(z2):35-39. |
[4] | Shin'ichi Matsumoto .Recent advances in automobile exhaust catalysts[J].Catalysis Today,2004(3/4):183-190. |
[5] | 徐鲁华,吴晓东,陈尊,翁端.锶掺杂对LaMnO3钙钛矿在稀燃条件下NO还原性能的影响[J].中国稀土学报,2002(z1):35-38. |
[6] | Saracco G;Scibilia G;Lannibello A;Baldi G.Methane cornbustion on Mg-doped LaCrO3 perovskite catalysts[J].Applied Catalysis B:Environmental,1996(08):229. |
[7] | 白树林,傅希贤,桑丽霞,杨秋华,王俊珍,曾淑兰.钙钛矿(ABO3)型复合氧化物的光催化活性变化趋势与分析[J].高等学校化学学报,2001(04):663-665. |
[8] | Zhang R D;Villanueva A;Alamdari H .Fe-based perovskites substituted by copper and palladium for NO + CO reaction[J].Journal of Catalysis,2006,242(01):241. |
[9] | Matsumoto S.;Suzuki H.;Ogai M.;Miyoshi N.;Ikeda Y. .NOx storage reduction catalyst for automotive exhaust with improved tolerance against sulfur poisoning[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2000(2/3):115-124. |
[10] | Tejuca L G;Fierro J L G;Tascon J M D .Structure and reactivity of perovskite-type oxides[J].Adv of Catal,1989,36(02):237. |
[11] | Zhang R D;Alamdari H;Kaliaguine S .Optimization of mixed catalysts for catalytic conversion of NO and C3 H6 in lean burn conditions[J].Int J Chem Reactor Eng,2007,5(A):70. |
[12] | Mahzoul H;Brilhac J F;Gilot P .Experimental and mechanistic study of NOx adsorption over NOx trap catalysts[J].Applied Catalysis B:Environmental,1999,20:47. |
[13] | Akama H;Matsushia K.Recent s lean Nox catalyst technologies for automobile exhaust control[J].Catalysis Surveys From Japan,1999(03):139. |
[14] | Zhang RD;Villanueva A;Alamdari H;Kaliaguine S .SCR of NO by propene over nanoscale LaMn1-xCuxO3 perovskites[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(1):85-97. |
[15] | Forni L;Oliva C;Vatti F P;Kandala M A Ezerets A M Vishniakov A V.La-Ce-Co perovskites as catalysts for exhaust gas depollution[J].Applied Catalysis B:Environmental,1996(07):269. |
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