以苯酚、溴丙烯、无水碳酸钾为起始原料通过O-烷化、Claisen重排制得邻烯丙基苯酚,使其和含氢硅油通过硅氢加成制得有机磷敏感材料聚甲基[3-(2-羟基)苯基]丙基硅氧烷(PMPS).将PMPS涂覆在石英晶体微天平(QCM)上,研究了其对神经性毒剂模拟剂甲基膦酸二甲酯(DMMP)和其它干扰气体的响应特性.结果表明在(5~70)×10-6范围内,传感器对DMMP的响应呈线性关系,灵敏度为12.4×106Hz.当测试蒸汽为饱和浓度时,传感器对DMMP的响应比其它干扰气体高6倍以上,表现出良好的选择性.
参考文献
[1] | McGill RA.;Chung R.;Shaffer RE.;DiLella D.;Stepnowski JL. Mlsna TE.;Venezky DL.;Dominguez D.;Nguyen VK. .The "NRL-SAWRHINO": a nose for toxic gases[J].Sensors and Actuators, B. Chemical,2000(1/3):10-13. |
[2] | Grate J W;Rose-Pehrsson S L;Venezky D L et al.[J].Analytical Chemistry,1993,65(14):1868-1881. |
[3] | Dominguez DD.;Nguyen V.;Tevault D.;McGill RA.;Chung R. .Evaluation of SAW chemical sensors for air filter lifetime and performance monitoring[J].Sensors and Actuators, B. Chemical,1998(3):186-190. |
[4] | Grate JW.;Nelson DA. .Sorptive polymeric materials and photopatterned films for gas phase chemical microsensors[J].Proceedings of the IEEE,2003(6):881-889. |
[5] | Zimmermann C;Mazein P;Rebière D et al.[J].IEEE SENSORS JOURNAL,2004,4(04):479-488. |
[6] | Rebière D;Déjous C;Pistré J et al.[J].Sensors and Actuators B:Chemical,1997,43:34-39. |
[7] | Grate JW.;Kaganove SN.;Wise BM.;Patrash SJ. .Hydrogen bond acidic polymers for surface acoustic wave vapor sensors and arrays[J].Analytical chemistry,1999(5):1033-1040. |
[8] | Ying Z;Jiang Y;Du X.[J].Sensors and Actuators B-Chemical,2007 |
[9] | Thomas R C;Hierlemann A;Staton A W et al.[J].Analytical Chemistry,1999,71(16):3615-3621. |
[10] | Nieuwenhuizen MS.;Harteveld JLN. .STUDIES ON A SURFACE ACOUSTIC WAVE (SAW) DOSIMETER SENSOR FOR ORGANOPHOSPHOROUS NERVE AGENTS[J].Sensors and Actuators, B. Chemical,1997(2/3):167-173. |
[11] | Prasad Taranekar;Chengyu Huang;Rigoberto C.Advincula .Pinacolyl methyl phosphonate(PMP)detection by molecularly imprinted polymers(MIP):A labile covalent bonding approach[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(19):6485-6490. |
[12] | Kiseleva M G;Nesterenko P N .[J].Journal of Chromatography A,2000,898:23-34. |
[13] | Mcgill R A;Abraham M H;Grate J W .[J].Chemtech,1994,24(09):27-37. |
[14] | Demathieu C;Chhimi M M;Lipskier J F .[J].Sensors and Actuators B-Chemical,2000,62(01):1-7. |
[15] | A Measurement System for Odor Classification Based on the Dynamic Response of QCM Sensors[J].IEEE Transactions on Instrumentation and Measurement,2003(4):1079-1086. |
[16] | Hierlemann A;Ricco A J;Bodenhofer K et al.[J].Analytical Chemistry,1996,68(05):3022-3035. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%