分别以毛竹和石油焦为炭前驱体,采用KOH活化法制备超级电容器用高比表面积活性炭材料,考察了碱/炭比对不同炭前驱体所制得的活性炭的孔结构、吸附性能和电容性能的影响.结果表明,在相同的碱/炭比下,竹基活性炭孔径<2nm的微孔较发达,而石油焦基活性炭孔径在2~50nm的中孔率较高.在适宜的工艺条件下,以毛竹为炭前驱体可制得比表面积为2610.7m2/g,比电容为206F/g的活性炭材料;以石油焦为炭前驱体可制得比表面积为2597.9m2/g,比电容为213F/g的活性炭材料.
参考文献
[1] | Shinji Nohara;Hajime Wada;Naoji Furukawa;Hiroshi Inoue;Masayuki Morita;Chiaki Iwakura .Electrochemical characterization of new electric double layer capacitor with polymer hydrogel electrolyte[J].Electrochimica Acta,2003(6):749-753. |
[2] | Tamai H;Kouzu M;Morita M et al.[J].Electrochemical and Solid-State Letters,2003,6:A214. |
[3] | Wu F C;Tseng R L;Hu C C .[J].Microporous and Mesoporous Materials,2005,80(1-3):95-106. |
[4] | Wang CC;Hu CC .Electrochemical catalytic modification of activated carbon fabrics by ruthenium chloride for supercapacitors[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(9):1926-1935. |
[5] | Alejandro Robau Sanchez;Alfredo Aguilar Elguezabal;Luis de La Torre Saenz .CO_2 activation of char from Quercus agrifolia wood waste[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(9):1367-1377. |
[6] | 王国庆,林忠富,左伟忠,王树学.超大容量双电层电容器主要技术参数的测试[J].电子元件与材料,2000(02):15-16,21. |
[7] | 梅建庭,白雪莲,齐磊.煤沥青制备高性能活性炭[J].炭素,2000(01):12-14. |
[8] | Yoshida A;Tanahashi I;Nishino A et al.[J].Carbon,1990,28(05):611-615. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%