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测定了纳滤膜在电解质水溶液中的流动电位.考察了盐溶液浓度、操作压力、离子种类和价态等对膜表面流动电位的影响.通过流动电位的测定可以得到纳滤膜的表面动电参数:Zeta电位和表面电荷密度.研究了浓度和压力对Zeta电位和电荷密度的影响.结果表明:纳滤膜表面流动电位的绝对值(|△E|)和表面Zeta电位的绝对值(|ζ|)均随电解质溶液浓度和压力的增加而减小;|△E|在不同电解质溶液中的顺序为:NaCl>MgCl2>KCl>KBr>Na2SO4>MeS04;表面电荷密度的绝对值(|σd|)随电解质溶液浓度的增加而增加,随压力的增加而下降.

参考文献

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