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以高质量GaN单晶基片作为衬底实现GaN的同质外延生长,是获得GaN半导体器件优异性能的基础.高质量GaN单晶基片的缺乏已成为国际范围制约GaN器件发展的瓶颈.在GaN体单晶的几种生长方法中,由于Na助熔剂法的生长条件相对温和且成本相对较低,近年来发展较快.本文从Na助熔剂法的原理、生长工艺、助熔剂种类以及得到晶体尺寸和质量等几方面进行了综述,分析了目前Na助熔剂法生长GaN单晶中的技术问题并提出了进一步研究的一些建议.

参考文献

[1] Hisanori Yamane;Masahiko Shimada;Simon J.Clarke .Preparation of GaN single crystals using a Na flux[J].Chemistry of Materials,1997(2):413-416.
[2] Yamane H.;Sekiguchi T.;DiSalvo FJ.;Shimada M. .Morphology and characterization of GaN single crystals grown in a Na flux[J].Journal of Crystal Growth,1998(1/2):8-12.
[3] Yamane H.;Endo T.;DiSalvo FJ.;Shimada M. .Polarity of GaN single crystals prepared with Na flux[J].Japanese Journal of Applied Physics,1998(6A):3436-3440.
[4] Y. Mori;M. Imade;K. Murakami;H. Takazawa;H. Imabayashi;Y. Todoroki;K. Kitamoto;M. Maruyama;M. Yoshimura;Y. Kitaoka;T. Sasaki .Growth of bulk GaN crystal by Na flux method under various conditions[J].Journal of Crystal Growth,2012(1):72-74.
[5] H. YAMANE;D. KINNO;M. SHIMADA .GaN single crystal growth from a Na-Ga melt[J].Journal of Materials Science,2000(4):801-808.
[6] Masato Aoki;Hisanori Yamane;Masahiko Shimada .Growth of GaN single crystals from a Na-Ga melt at 750 deg C and 5 MPa of N_2[J].Journal of Crystal Growth,2000(1):7-12.
[7] 周明斌,李振荣,范世(马岂),徐卓.7 MPa氮压下Na助熔剂法生长GaN晶体的研究[J].人工晶体学报,2013(02):203-207,225.
[8] Imade, M.;Murakami, K.;Matsuo, D.;Imabayashi, H.;Takazawa, H.;Todoroki, Y.;Kitamoto, A.;Maruyama, M.;Yoshimura, M.;Mori, Y. .Centimeter-sized bulk GaN single crystals grown by the Na-flux method with a necking technique[J].Crystal growth & design,2012(7):3799-3805.
[9] Yamane H.;Sekiguchi T.;Shimada M.;Kajiwara T. .Zinc-blende-type cubic GaN single crystals prepared in a potassium flux[J].Japanese journal of applied physics,2000(2B):L146-L148.
[10] Hisanon yamane;Masahiko Shimada;Francis J. DiSalvo .Growth of zinc-blend-type structure GaN from a Na-Ga melt[J].Materials Letters,2000(1/2):66-70.
[11] Youting Song;Wenjun Wang;Wenxia Yuan;Xing Wu;Xiaolong Chen .Bulk GaN single crystals: growth conditions by flux method[J].Journal of Crystal Growth,2003(3/4):275-278.
[12] W.J. Wang;X.L. Chen;Y.T. Song;W.X. Yuan;Y.G. Cao;X. Wu .Assessment of Li-Ga-N ternary system and GaN single crystal growth[J].Journal of Crystal Growth,2004(1/3):13-16.
[13] Morishita M;Kawamura F;Kawahara M;Yoshimura M;Mori Y;Sasaki T .Promoted nitrogen dissolution due to the addition of Li or Ca to Ga-Na melt; some effects of additives on the growth of GaN single crystals using the sodium flux method[J].Journal of Crystal Growth,2005(1/2):91-99.
[14] Fumio Kawamura;Masanori Morishita;Masaki Tanpo;Mamoru Imade;Masashi Yoshimura;Yasuo Kitaoka;Yusuke Mori;Takatomo Sasaki .Effect of carbon additive on increases in the growth rate of 2 in GaN single crystals in the Na flux method[J].Journal of Crystal Growth,2008(17):3946-3949.
[15] Mamoru Imade;Yasuhiro Hirabayashi;Yusuke Konishi;Hiroshi Ukegawa;Naoya Miyoshi;Masashi Yoshimura;Takatomo Sasaki;Yasuo Kitaoka;Yusuke Mori .Growth of Large GaN Single Crystals on High-Quality GaN Seed by Carbon-Added Na Flux Method[J].Applied physics express,2010(7):75501.1-75501.3.
[16] Aoki M.;Yamane H.;Shimada M.;Sarayama S.;DiSalvo FJ. .GaN single crystal growth using high-purity Na as a flux[J].Journal of Crystal Growth,2002(1/2):70-76.
[17] Mamoru Imade;Yusuke Konishi;Hideo Takazawa .Control of the growth habit in the Na flux growth of GaN single crystals[J].Materials Science Forum,2012(Pt.2):1291-1294.
[18] Masato Aoki;Hisanori Yamane;Masahiko Shimada;Seiji Sarayama;Hirokazu Iwata;Francis J. DiSalvo .Single crystal growth of GaN by the temperature gradient Na flux method[J].Journal of Crystal Growth,2004(4):461-466.
[19] Gejo R;Kawamura F;Kawahara M;Yoshimura M;Kitaoka Y;Mori Y;Sasaki T .Effect of thermal convection on liquid phase epitaxy of GaN by Na flux methodn[J].Japanese journal of applied physics,2007(12):7689-7692.
[20] Fumio Kawamura;Masaki Tanpo;Naoya Miyoshi;Mamoru Imade;Masashi Yoshimura;Yusuke Mori;Yasuo Kitaoka;Takatomo Sasaki .Growth of GaN single crystals with extremely low dislocation density by two-step dislocation reduction[J].Journal of Crystal Growth,2009(10):3019-3024.
[21] Masayuki Imanishi;Kosuke Murakami;Hiroki Imabayashi;Hideo Takazawa;Yuma Todoroki;Daisuke Matsuo;Mihoko Maruyama;Mamoru Imade;Masashi Yoshimura;Yusuke Mori .Coalescence Growth of Dislocation-Free GaN Crystals by the Na-Flux Method[J].Applied physics express,2012(9):95501.1-95501.3.
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