按照阴离子配位机理金属卟啉络合体系在引发环状化合物的开环聚合,形成窄分布,可控分子量聚合物方面具有显著优越性.文中在分析该引发体系结构特点的基础上,综述了金属卟啉络合体系的催化机理,开环聚合方式以及与该体系有关的新的催化合成方法.
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