溶液电沉积法是一种具有沉积时间短,可以常温沉积以及沉积物在基底上附着力高等优点的薄膜制备方法.本文用水合肼增溶苝酰亚胺类化合物(PTCDI)的方法制备了可用于溶液电沉积的苝酰亚胺类化合物溶液.用紫外-可见分光光度法(UV-Vis)对溶解的过程进行了表征,并用顺磁共振(ESR)验证了水合肼对PTCDI的增溶过程实质上是化学反应过程.在制备苝酰亚胺类化合物溶液的基础上,采用阳极电沉积法在ITO导电玻璃上沉积出了薄膜.采用UV-Vis,扫描电镜(SEM)和X射线衍射仪(XRD)对薄膜进行了表征,证实得到了表面较为平整、具有可控结晶结构和形貌的PTCDI薄膜以及具有较宽光谱吸收范围的复合薄膜.
参考文献
| [1] | 沈永嘉,许煦,张忠胜.（艹北）系颜料的品种与性能[J].化工科技市场,2001(06):10-12,13. |
| [2] | Ng AMC;Djurisic AB;Tam KH;Kwok WM;Chan WK;Tam WY;Phillips DL;Cheah KW .Organic nanoclusters on inorganic nanostructures for tailoring the emission properties of organic materials[J].Advanced functional materials,2008(4):566-574. |
| [3] | Valentin D. Mihailetchi;Hangxing Xie;Bert de Boer;L. Jan Anton Koster;Paul W. M. Blom .Charge Transport and Photocurrent Generation in Poly(3-hexylthiophene): Methanofullerene Bulk-Heterojunction Solar Cells[J].Advanced functional materials,2006(5):699-708. |
| [4] | Xue CM;Chen MZ;Jin S .Synthesis and characterization of the first soluble nonracemic chiral main-chain perylene tetracarboxylic diimide polymers[J].Polymer: The International Journal for the Science and Technology of Polymers,2008(24):5314-5321. |
| [5] | Liu YL;Li HX;Tu DY;Ji ZY;Wang CS;Tang QX;Liu M;Hu WP;Liu YQ;Zhu DB .Controlling the growth of single crystalline nanoribbons of copper tetracyanoquinodimethane for the fabrication of devices and device arrays[J].Journal of the American Chemical Society,2006(39):12917-12922. |
| [6] | Ohmori Y;Itoh E;Miyairi K .Photovoltaic properties of phthalocyanine based p-n diode evaporated onto titanium dioxide[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):369-373. |
| [7] | Schlettwein D.;Schilling B.;Fritz T.;Armstrong NR.;Back A. .Ultrathin films of perylenedianhydride and perylenebis(dicarboximide) dyes on (001) alkali halide surfaces[J].Chemistry of Materials,1998(2):601-612. |
| [8] | Marcon, RO;Brochsztain, S .Aggregation of 3,4,9,10-Perylenediimide Radical Anions and Dianions Generated by Reduction with Dithionite in Aqueous Solutions[J].The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory,2009(9):1747-1752. |
| [9] | Gosztola David. .Excited Doublet States of Electrochemically Generated Aromatic Imide and Diimide Radical Anions[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2000(28):6545-6551. |
| [10] | Rodrigo O. Marcon;Sergio Brochsztain .Highly Stable 3,4,9,10-Perylenediimide Radical Anions Immobilized in Robust Zirconium Phosphonate Self-Assembled Films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(24):11972-11976. |
| [11] | Che YK;Datar A;Yang XM;Naddo T;Zhao JC;Zang L .Enhancing one-dimensional charge transport through intermolecular pi-electron delocalization: Conductivity improvement for organic nanobelts[J].Journal of the American Chemical Society,2007(20):6354-6355. |
| [12] | Frank Wurthner .Perylene bisimide dyes as versatile building blocks for functional supramolecular architectures[J].Chemical communications,2004(14):1564-1579. |
| [13] | Ajay K. Pandey;Sylvie Dabos-Seignon;Jean-Michel Nunzi .Pentacene: PTCDI-C_(13)H_(27) molecular blends efficiently harvest light for solar cell applications[J].Applied physics letters,2006(11):113506-1-113506-2-0. |
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