考察了Br(o)nsted酸性离子液体同时作为溶剂和催化剂催化异丁醛和叔丁醇缩合制备 2,5-二甲基-2,4-己二烯的反应性能.结果表明,Br(o)nsted酸性离子液体具有良好的催化性能,反应后反应产物与离子液体自动分层易分离,离子液体经过真空干燥处理后可以作为溶剂和催化剂循环使用.调变离子液体中的阳离子或阴离子的结构对催化性能有较大的影响.
参考文献
| [1] | Dumitriu E.;Kaliaguine S.;On DT. .ISOPRENE BY PRINS CONDENSATION OVER ACIDIC MOLECULAR SIEVES[J].Journal of Catalysis,1997(1):150-160. |
| [2] | Dumitriu E;Hulea V;Fechete I;Catrinescu C Auroux A Lacaze J F Cuimon C .[J].Applied Catalysis A:General,1999,181(01):15. |
| [3] | Noller C K.Chemistry of Organic Compounds[M].London:Saunders,1965 |
| [4] | Harper S H;Reed H W B;Thompson R A .[J].Journal of the Science of Food and Agriculture,1951,2(02):94. |
| [5] | Takagi K;Murakami M;Manabe K .[P].DE 2243701,1973. |
| [6] | Yamaguchi T;Nishimichi C .[J].Catalysis Today,1993,16(3-4):555. |
| [7] | Higashio Y;Takahashi K .[P].EP 0215567,1987. |
| [8] | Yamaguchi T;Nishimichi C;Kubota A .[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1991,36(04):640. |
| [9] | Iizuka T;Ogasawara K;Tanabe K .[J].Bulletin of the Chemical Society of Japan,1983,56(10):2927. |
| [10] | Ogasawara K;Iizuka T;Tanabe K.[J].Chemistry Letters,1984(04):645. |
| [11] | Wang H;Liu Zh M;Sun Ch L;Wang G W .[J].Catalysis Today,2004,93-95:425. |
| [12] | Wang H;Liu Zh M;Sun Ch L;Wang G W .[J].Catalysis Communications,2004,5(01):41. |
| [13] | Welton T .[J].Chemical Reviews,1999,99(08):2071. |
| [14] | Wasserscheid P.;Keim W. .Ionic liquids - New "solutions" for transition metal catalysis [Review][J].Angewandte Chemie International Edition,2000(21):3773-3789. |
| [15] | Earle M J;Seddon K R .[J].Pure and Applied Chemistry,2000,72(07):1391. |
| [16] | Gordon C M .[J].Applied Catalysis A:General,2001,222(1-2):101. |
| [17] | Sheldon R.[J].Chemical Communications,2001(23):2399. |
| [18] | Olivier-Bourbigou H;Magan L .[J].Journal of Molecular Catalysis A:Chemical,2002,182-183:419. |
| [19] | Dupont J;de Souza R F;Suarez P A Z .[J].Chemical Reviews,2002,102(10):3667. |
| [20] | Zhao D B;Wu M;Kou Y;Min En Z .[J].Catalysis Today,2002,74(1-2):157. |
| [21] | Cole A C;Jensen J L;Ntai I;Tran K L T Weaver K J Forbes D C Davis J H .[J].Journal of the American Chemical Society,2002,124(21):5962. |
| [22] | Zhu H P;Yang F;Tang J;He M Y .[J].Green Chemistry,2003,5(01):38. |
| [23] | Gui J Zh;Cong X H;Liu D;Zhang X T Hu Zh D Sun Zh L .[J].Catalysis Communications,2004,5(09):473. |
| [24] | Gu Y L;Shi F;Deng Y Q .[J].Catalysis Communications,2003,4(11):597. |
| [25] | Gu Y L;Shi F;Deng Y Q .[J].Journal of Molecular Catalysis A:Chemical,2004,212(1-2):71. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%