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以钛板为基体,通过热分解H2IrCl6,TaCl5和H2SiO3的混合涂液制备了Ti/IrO2-Ta2O5-SiO2阳极,研究了SiO2含量对Ti/IrO2-Ta2O5-SiO2阳极电催化活性及稳定性的影响.结果表明:掺杂SiO2后Ti/IrO2-Ta2O5-SiO2阳极电催化活性降低;适量SiO2可以提高Ti/IrO2-Ta2O5-SiO2阳极稳定性.当涂液中Si的摩尔分数为5%时,Ti/IrO2-Ta2O5-SiO2阳极的稳定性最好;当Si的摩尔分数达到20%时,其稳定性低于未掺SiO2的电极的稳定性.

参考文献

[1] S. Trasatti .Electrocatalysis: understanding the success of DSA[J].Electrochimica Acta,2000(15/16):2377-2385.
[2] 胡耀红,陈力格.DSA涂层钛阳极及其应用[J].电镀与涂饰,2003(05):58-59.
[3] KRISTOF J;MINK J;DE BATTISTI A et al.Emission FTIR studies on the formation mechanism of IrO2/TiO2 based coatings[J].Electrochimica Acta,1994,39(11/12):1531-1535.
[4] BENEDETTI A;RIELLO P;BATTAGLIN G et al.Physicoehemical properties of thermally prepared Ti-supported IrO2+ZrO2 electrocatalysts[J].Journal of Electroanalytical Chemistry,1994,376(1/2):195-202.
[5] TEREZO A J;PEREIRA E C .Fractional factorial design applied to investigate properties of Ti/IrO2-Nb2O5 electrodes[J].Electrochimica Acta,2000,45(25/26):4351-4358.
[6] VERCESI G P;SALAMIN J-Y;COMNINELLIS CH .Morphological and microstruetural the Ti/IrO2-Ta2O5 electrode:effect of the preparation temperature[J].Electrochimica Acta,1991,36(5/6):991-998.
[7] COMNINELLIS CH;VERCESI G P .Characterization of DSA-type oxygen evolving electrodes:choice of a coating[J].Journal of Applied Electrochemistry,1991,21(04):335-345.
[8] 陶自春,罗启富,潘建跃.铱系涂层钛阳极的研究进展[J].材料科学与工程学报,2003(01):138-142.
[9] 刘雪华,唐电.含硅钛阳极的制备及其电催化性能研究[J].材料保护,2007(09):7-9.
[10] 唐电.钛阳极的制备及其纳米结构涂层的分析[J].中国有色金属学报,1996(01):89-92.
[11] Guido Saracco;Lisa Solarino;Riccardo Aigotti;Vito Specchia Mario Maja .Electrochemical oxidation of organic pollutants at low electrolyte concentrations[J].Electrochimica Acta,2000(2/3):373-380.
[12] 刘雪华,唐电.RuO2-SiO2二元氧化物被覆钛涂层的制备[J].材料热处理学报,2007(z1):198-201.
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