采用半连续种子乳液聚合方法,在十二烷基硫酸钠(SDS)/辛基苯基聚氧乙烯醚(OP-10)复合乳化剂的作用下,合成了以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)和甲基丙烯酸十二氟庚酯(Actyflon-G04)为原料的水性核壳型结构的含氟丙烯酸酯聚合物乳液.并利用FT-IR、SEM-EDX、TEM、DSC等手段研究了乳液的稳定性、乳胶粒子的结构和形态,分析了氟单体含量和复合乳化剂含量对聚合物乳液性能及成膜性能的影响.
参考文献
[1] | Casazza E.;Mariani A.;Ricco L.;Russo S. .Synthesis, characterization, and properties of a novel acrylic terpolymer with pendant perfluoropolyether segments[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(4):1207-1214. |
[2] | Ciardelli F.;Dimirabello LM.;Passaglia E.;Giancristoforo S.;Castelvetro V.;Ruggeri G.;Aglietto M. .NEW FLUORINATED ACRYLIC POLYMERS FOR IMPROVING WEATHERABILITY OF BUILDING STONE MATERIALS[J].Progress in Organic Coatings: An International Review Journal,1997(1/4):43-50. |
[3] | Allen N S;Regan C J;Dunk W A E et al.[J].Polymer Degradation and Stability,1997,58:149. |
[4] | Matteo V .[J].Progress in Organic Coatings,2000,40:225. |
[5] | Takashi T .[J].Progress in Organic Coatings,2000,40:185. |
[6] | 赵兴顺,丁小斌,郑朝晖,潘毅,朱珠,戴静,彭宇行.含氟丙烯酸酯共聚乳液的制备及表征[J].功能高分子学报,2003(04):436-440. |
[7] | 谭必恩;张洪涛;胡芳 等.[J].高分子材料科学与工程,2005,16(03):39. |
[8] | Cim C U;Lee J M;Ihm S K .[J].Journal of Fluorine Chemistry,1999,96(11) |
[9] | Lucia T;Tommaso P;Valter C et al.[J].Journal of Cultural Heritage,2002,3:309. |
[10] | Poggio T.;Kapeliouchko V.;Arcella V.;Marchese E. .Multimodal fluoropolymer dispersions[J].Progress in Organic Coatings: An International Review Journal,2003(2/4):310-315. |
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