欢迎登录材料期刊网

材料期刊网

高级检索

采用双螺杆加工过程中的机械力引发同时添加引发剂的双重引发方法,研究了引发剂的用量、螺杆转速和接枝反应温度对马来酸酐接枝POE产物的接枝率、熔融指数的影响.对单纯采用引发剂引发方法和引发剂与机械力双重引发方法所得接枝产物增韧PA66的效果也进行了比较.

Grafting of maleic anhydride(MAH) onto polyolefin elastomers(POE) performed in melt state through a compound initiation system of increasing the screw rotation speed of co-rotating twin-screw extruder and adding a certain initiator are investigated. The effects of screw rotation speed, initiator content and grafting temperature on the grafting level, melt flow index and gel content of the grafted product(POE-g-MAH), and the effects of toughening PA66 by the simple initiator and the compound initiation are studied.

参考文献

[1] 张金柱.新型热塑性弹性体POE的性能及其在PP增韧改性中的应用[J].塑料科技,1999(02):5-7.
[2] 龚春锁,揣成智.POE熔融挤出接枝MAH的研究[J].上海塑料,2007(04):27-29.
[3] 胥成,郭强,汪晓明.反应挤出法制备马来酸酐接枝POE[J].塑料,2006(01):54-57.
[4] 冯威;武德珍 等.乙烯-1-辛烯共聚物熔融接枝马来酸酐德研究[J].北京化工大学学报,1998,25(04):33.
[5] 王国忠,章永化,游华燕,胡长存,陈志华.马来酸酐接枝POE改性SAN树脂的制备与性能研究[J].塑料工业,2006(05):23-25.
[6] Adams CH.;Klein PG.;Mcleish TCB.;Richards RW.;Hutchings LR. .SYNTHESIS AND DYNAMIC RHEOLOGICAL BEHAVIOR OF POLYBUTADIENE STAR POLYMERS[J].Macromolecules,1996(17):5717-5722.
[7] Roover B D;Sclavons M;Carlier V et al.Moleculer characterization of maleic anhydride-functionalized polypropylene[J].Polymer Science part A:Polymer Chemistry,1995,33:829.
[8] 张云灿,李惠林.超声引发马来酸酐接枝HDPE、LLDPE和EPDM研究[J].高分子材料科学与工程,2002(02):159-164.
[9] Heinen W.;Wenzel CB.;Degroot HJM.;Lugtenburg J. Vanduin M.;Rosenmoller CH. .C-13 NMR STUDY OF THE GRAFTING OF MALEIC ANHYDRIDE ONTO POLYETHENE, POLYPROPENE, AND ETHENE-PROPENE COPOLYMERS[J].Macromolecules,1996(4):1151-1157.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%