Two different PAN precursors with various comonomers were wet-spun.The properties and struc tural changes of PAN precursors and their evolution during preoxidation and carbonization process were characterized by the use of DSC, FTIR and traditional parameters, e g, tensile strength.It is demonstrated that acrylamide( AAM) is very effective to make the DSC peak be separated compared to methyl acrylate( MA ).As a result,carbon fibers developed from AAM-contained precursors have a better tetacity compared to those developed from MAcontained ones.
参考文献
[1] | S. CHAND .Review Carbon fibers for composites[J].Journal of Materials Science,2000(6):1303-1313. |
[2] | A K Gupta;D K Paliwal;P Bajaj .Acrylic Precursors for Carbon Fibers[J].Journal of Macromolecular Science:Reviews in Macromolecular Chemistry and Physics,1991,C31:1-89. |
[3] | Jin-Shy Tsai .Comparison of batch and continuous oxidation processes for producing carbon fibre based on PAN fibre[J].Journal of Materials Science Letters,1997(5):361-362. |
[4] | S C Martin;J J Liggat;C E Snape .In situ NMR Investigation into the Thermal Degradation and Stabilization of PAN[J].Polymer Degradation and Stability,2001,74:407-412. |
[5] | Bahrami SH.;Bajaj P.;Sen K. .Thermal behavior of acrylonitrile carboxylic acid copolymers[J].Journal of Applied Polymer Science,2003(3):685-698. |
[6] | Hideto Kakida;Kohji Tashiro .Mechanism and Kinetics of Stabilization Reactions of PAN and Related Copolym.ers[J].Polymer Journal,1997,29:557-562. |
[7] | T Usami;T Itoh;H Ohtani;S Tsuge .Structural Study of PAN Fibers During Oxidative Thermal Degration by Pyrolysis-gas Chromatography,Solid-state C Nuclear Magnetic Resonance,and Fourier Transform Infrared Spectroscopy[J].MACROMOLECULES,1990,23:2460-2465. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%