介绍了聚烯烃类隔膜在液态锂离子二次电池中的重要作用、制备方法及其优缺点和面对越来越广泛的应用需求该类隔膜所存在的主要不足;重点论述了针对目前聚烯烃隔膜低表面能、难以充分润湿及耐热性差的问题而进行改性的研究成果和现状;总结了所采用的物理涂覆、化学接枝、共混及凝胶填充等改性方法及其存在优缺点;最后提出了对于聚烯烃类隔膜改性未来发展趋势的展望.
参考文献
| [1] | 樊孝红,蔡朝辉,吴耀根,叶舒展,徐冰.锂离子电池隔膜的研究及发展现状[J].中国塑料,2008(12):11-15. |
| [2] | 任小龙;刘渝洁;冯勇刚 等.电池隔膜的制备方法研究进展[J].绝缘材料,2007,40:6. |
| [3] | 叶舒展;蔡朝辉;黄海星 等.湿法生产锂离子电池隔膜流程简介[J].塑料制造,2009,3:64. |
| [4] | Jeong Y B;Kim D W .The role of an adhesive gel-forming polymer coated on separator for rechargeable lithium metal polymer cells[J].Solid State Ionics,2005,176:47-51. |
| [5] | Sohn JY;Gwon SJ;Choi JH;Shin J;Nho YC .Preparation of polymer-coated separators using an electron beam irradiation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2008(23):4994-5000. |
| [6] | Joon-Yong Sohn;Jong Su Im;Sung-Jin Gwon .Preparation and characterization of a PVDF-HFP/PEGDMA-coated PE separator for lithium-ion polymer battery by electron beam irradiation[J].Radiation Physics and Chemistry,2009(7/8):505-508. |
| [7] | Ki Jae Kim;Jae-Hun Kim;Min-Sik Park;Hyuk Kwon Kwon;Hansu Kim;Young-Jun Kim .Enhancement of electrochemical and thermal properties of polyethylene separators coated with polyvinylidene fluoride-hexafluoropropylene co-polymer for Li-ion batteries[J].JOURNAL OF POWER SOURCES,2012(Jan.15):298-302. |
| [8] | Jang-Hoon Park;Woong Park;Jong Hun Kim;Dongjo Ryoo;Hoon Sik Kim;Yeon Uk Jeong;Dong-WonKim;Sang-YoungLee .Close-packed poly(methyl methacrylate) nanoparticle arrays-coated polyethylene separators for high-power lithium-ion polymer batteries[J].Journal of Power Sources,2011(16):7035-7038. |
| [9] | Li, B;Liu, WP;Jiang, ZY;Dong, X;Wang, BY;Zhong, YR .Ultrathin and Stable Active Layer of Dense Composite Membrane Enabled by Poly(dopamine)[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(13):7368-7374. |
| [10] | Xi Zhenyu;Xu Youyi;Zhu Liping et al.A facile method of surface modification for hydrophobic polymer membranes based on the adhesive behavior of poly (DOPA) and poly(dopamine)[J].Journal of Membrane Science,2009,327:244-253. |
| [11] | Zhu, L.-P.;Jiang, J.-H.;Zhu, B.-K.;Xu, Y.-Y. .Immobilization of bovine serum albumin onto porous polyethylene membranes using strongly attached polydopamine as a spacer[J].Colloids and Surfaces, B. Biointerfaces,2011(1):111-118. |
| [12] | Jiang, J.;Zhu, L.;Zhu, B.;Xu, Y. .Surface characteristics of a self-polymerized dopamine coating deposited on hydrophobic polymer films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(23):14180-14187. |
| [13] | Myung-Hyun Ryou;Yong Min Lee;Jung-Ki Park;Jang Wook Choi .Mussel-Inspired Polydopamine-Treated Polyethylene Separators for High-Power Li-Ion Batteries[J].Advanced Materials,2011(27):3066-3070. |
| [14] | J. M. Ko;E. G. Min;D. -W. Kim;K. S. Ryu;K. M. Kim;Y. G. Lee;S. H. Chang .Thin-film type Li-ion battery, using a polyethylene separator grafted with glycidyl methacrylate[J].Electrochimica Acta,2004(2/3):367-370. |
| [15] | Kun Gao;Xinguo Hu;Tingfeng Yi;Changsong Dai .PE-g-MMA polymer electrolyte membrane for lithium polymer battery[J].Electrochimica Acta,2006(2):443-449. |
| [16] | Li, SD;Gao, K .The study on methyl methacrylate graft-copolymerized composite separator prepared by pre-irradiation method for Li-ion batteries[J].Surface & Coatings Technology,2010(16/17):2822-2828. |
| [17] | Jun Young Kim;Yongbeom Lee;Dae Young Lim .Plasma-modified polyethylene membrane as a separator for lithium-ion polymer battery[J].Electrochimica Acta,2009(14):3714-3719. |
| [18] | Jun Young Lee;Yong Min Lee;Bhaskar Bhattacharya;Young-Chang Nho;Jung-Ki Park .Separator grafted with siloxane by electron beam irradiation for lithium secondary batteries[J].Electrochimica Acta,2009(18):4312-4315. |
| [19] | Jun Young Lee;Bhaskar Bhattacharya;Young-Chang Nho;Jung-Ki Park .New separator prepared by electron beam irradiation for high voltage lithium secondary batteries[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2009(14):2390-2394. |
| [20] | Gwon SJ;Choi JH;Sohn JY;An SJ;Ihm YE;Nho YC .Radiation grafting of methyl methacrylate onto polyethylene separators for lithium secondary batteries[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2008(15):3387-3391. |
| [21] | Sung-Jin Gwon;Jae-Hak Choi;Joon-Yong Sohn .Battery performance of PMMA-grafted PE separators prepared by pre-irradiation grafting technique[J].Journal of industrial and engineering chemistry,2009(5):748-751. |
| [22] | Sung-Jin Gwon;Jae-Hak Choi;Joon-Yong Sohn;Young-Eon Ihm;Young-Chang Nho .Preparation of a new micro-porous poly(methyl methacrylate)-graftedpolyethylene separator for high performance Li secondary battery[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2009(19):3309-3313. |
| [23] | Wongchitphimon S;Wang Rong;Jiraratananon R et al.Effect of polyethylene glycol (PEG) as an additive on the fabrication of polyvinylidene fluoride-cohexafluropropylene (PVDF-HFP) asymmetric microporous hollow fiber membranes[J].Journal of Membrane Science,2011,369:329-338. |
| [24] | Oh S J;Kim N;Lee Y T .Preparation and characterization of PVDF/TiO2 organic-inorganic composite membranes for fouling resistance improvement[J].Journal of Membrane Science,2009,345:13-25. |
| [25] | Zhang Chunfang;Bai Yunxiang;Sun Yuping .Preparation of hydrophilic HDPE porous membranes via thermally induced phase separation by blending of amphiphilic PE-b-PEG copolymer[J].Journal of Membrane Science,2010,365:216-224. |
| [26] | Zhang Mei;Zhang Chunfang;Yao Zhikan et al.Preparation of high density polyethylene/polyethylene block-poly(ethylene glycol) copolymer blend porous membranes via thermally induced phase separation process and their properties[J].Chinese Journal of Polymer Science,2010,28:337-346. |
| [27] | 石俊黎,姚之侃,方立峰,朱宝库,徐又一.热致相分离法制备锂离子电池用HDPE/PE-PEG共混微孔膜[C].2009全国功能材料科技与产业高层论坛论文集,2009:625-627. |
| [28] | Li Hao;Ma Xiaoting;Shi Junli et al.Preparation and properties of poly(ethylene oxide)gel filled polypropylene separators and their corresponding gel polymer electrolytes for Li-ion batteries[J].Electrochimica Acta,2011,56:2641-1647. |
| [29] | Goodenough J B;Kim Y .Challenge for rechargeable Li batteries[J].Chemistry of Materials,2010,22:587. |
| [30] | Y. S. Chung;S. H. Yoo;C. K. Kim .Enhancement of Meltdown Temperature of the Polyethylene Lithium-Ion Battery Separator via Surface Coating with Polymers Having High Thermal Resistance[J].Industrial & Engineering Chemistry Research,2009(9):4346-4351. |
| [31] | Yoo S H;Kim C K .Article enhancement of the meltdown temperature of a lithium ion battery separator via a nanocomposite coating[J].Industrial and Engineering Chemistry Research,2009,48:9936-9941. |
| [32] | Sang Chul Roh;Kwon Won Song;C. K. Kim .Effects of Nonsolvent Molecular Structure and Its Content on the Formation of the Macroporous Polyarylate Layer Coated onto the Polyethylene Separator[J].Industrial & Engineering Chemistry Research,2011(22):12596-12605. |
| [33] | Song K W;Kim C K .Coating with macroporous polyarylate via a nonsolvent induced phase separation process for enhancement of polyethylene separator thermal stability[J].Journalof Membrane Science,2010,352:239-246. |
| [34] | Jang-Hoon Park;Joo-Hyun Cho;Woong Park;Dongjo Ryoo;Su-Jin Yoon;Jong Hun Kim;Yeon Uk Jeong;Sang-Young Lee .Close-packed SiO_2/poly(methyl methacrylate) binary nanoparticles-coated polyethylene separators for lithium-ion batteries[J].Journal of Power Sources,2010(24):8306-8310. |
| [35] | Jeong H S;Hong S C;Lee S Y .Effect of microporous structure on thermal shrinkage and electrochemical performance of Al2 O3/poly (vinylidene fluoridehexafluoropropylene) composite separators for lithim-ion batteries[J].Journal of Membrane Science,2010,364:177-182. |
| [36] | Effect of phase inversion on microporous structure development of Al_2O_3/poly(vinylidene fluoride-hexafluoropropylene)-based ceramic composite separators for lithium-ion batteries[J].Journal of Power Sources,2010(18):6116. |
| [37] | Jeong H S;Lee S Y;Closely packed SiO2 .nanoparticles/poly (vinylidene fluoride-hexafluoropropylene)layers-coated polyethylene separators for lithium-ion batteries[J].Journal of Power Sources,2011,196:6716-6722. |
| [38] | Enhancement of thermal stability and cycling performance in lithium-ion cells through the use of ceramic-coated separators[J].Journal of Power Sources,2010(18):6192. |
| [39] | B.Croonenborghs;M.A.Smith;P.Strain .X-ray versus gamma irradiation effects on polymers[J].Radiation Physics and Chemistry,2007(11/12):1676-1678. |
| [40] | Sohn JY;Gwon SJ;Choi JH;Shin J;Nho YC .Preparation of polymer-coated separators using an electron beam irradiation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2008(23):4994-5000. |
| [41] | Effect of gamma ray irradiation on thermal and electrochemical properties of polyethylene separator for Li ion batteries[J].Journal of Power Sources,2010(18):6075. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%