综述了核壳型聚醋酸乙烯酯(PVAc)基乳液乳胶粒形态控制机理的研究进展,重点评述了核壳型PVAc基乳胶粒形态控制中热力学与动力学的控制作用,并对核壳型PVAc基乳胶粒形态演变模型进行了概述.PVAc基乳胶粒的热力学性质决定其最终平衡形态,而动力学条件则决定其形态演变历程.在实际聚合反应中,核壳型PVAc基乳胶粒形态是由热力学因素和动力学因素共同决定的.核壳型PVAc基乳胶粒形态演变模型的建立有助于热力学与动力学的有机结合,为深入理解核壳型PVAc基乳胶粒形态演变及其控制提供理论依据.
参考文献
| [1] | Zhang, S.-F.;Wang, R.-M.;He, Y.-F.;Song, P.-F.;Wu, Z.-M. .Waterborne polyurethane-acrylic copolymers crosslinked core-shell nanoparticles for humidity-sensitive coatings[J].Progress in Organic Coatings: An International Review Journal,2013(4):729-735. |
| [2] | Fu, S.;Tian, A.;Du, C.;Wang, C. .Preparation of core-shell latex for the pigmented ink of textile inkjet printing[J].Journal of Applied Polymer Science,2013(4):2678-2683. |
| [3] | Xu, P.;Chang, K.;Park, Y.I.;Zhang, B.;Kang, L.;Du, Y.;Iyer, R.S.;Wang, H.-L. .Conjugated polymer mediated synthesis of nanoparticle clusters and core/shell nanoparticles[J].Polymer: The International Journal for the Science and Technology of Polymers,2013(2):485-489. |
| [4] | Guo-Dong Fu;Guo Liang Li;K.G. Neoh .Hollow polymeric nanostructures—Synthesis, morphology and function[J].Progress in Polymer Science,2011(1):127-167. |
| [5] | Yao, D.;Guo, Y.;Chen, S.;Tang, J.;Chen, Y. .Shaped core/shell polymer nanoobjects with high antibacterial activities via block copolymer microphase separation[J].Polymer: The International Journal for the Science and Technology of Polymers,2013(14):3485-3491. |
| [6] | Alireza Kaboorani;Bernard Riedl .Improving performance of polyvinyl acetate (PVA) as a binder for wood by combination with melamine based adhesives[J].International Journal of Adhesion & Adhesives,2011(7):605-611. |
| [7] | Warren J.Grigsby;Christopher J.Ferguson;Robert A.Franich;Gregory T.Russell .Evaluation of latex adhesives containing hydrophobic cores and poly(vinyl acetate)shells:potential to improve poly(vinyl acetate)performance[J].International Journal of Adhesion & Adhesives,2005(2):127-137. |
| [8] | Afeesh R. Unnithan;Nasser A.M. Barakat;M.F. Abadir.Novel CdPdS/PVAc core-shell nanofibers as an effective photocatalyst for organic pollutants degradation[J].Journal of molecular catalysis, A. Chemical,2012:186-194. |
| [9] | Ying, X.;Qi, L.;Li, X.;Zhang, W.;Cheng, G. .Stimuli-responsive recognition of BSA-imprinted poly vinyl acetate grafted calcium alginate core-shell hydrogel microspheres[J].Journal of Applied Polymer Science,2013(5):3898-3909. |
| [10] | Ma, J.-Z.;Liu, Y.-H.;Bao, Y.;Liu, J.-L.;Zhang, J..Research advances in polymer emulsion based on "core-shell" structure particle design[J].Advances in colloid and interface science,2013:118-131. |
| [11] | Ghosh Chaudhuri, R.;Paria, S. .Core/shell nanoparticles: Classes, properties, synthesis mechanisms, characterization, and applications[J].Chemical Reviews,2012(4):2373-2433. |
| [12] | C.S.Chern .Emulsion polymerization mechanisms and kinetics[J].Progress in Polymer Science,2006(5):443-486. |
| [13] | 赵科,孙培勤,刘大壮.核壳乳液聚合乳胶粒形态理论研究进展[J].高分子材料科学与工程,2003(06):14-17,22. |
| [14] | Sun PQ.;Zhao K.;Liu DH.;Huo DX. .Prediction and experiment of core-shell particle morphology of vinyl acetate and butyl acrylate[J].Journal of Applied Polymer Science,2002(13):2930-2937. |
| [15] | Zhao K.;Sun PQ.;Liu DZ.;Dai G. .The formation mechanism of poly(vinyl acetate)/poly(butyl acrylate) core/shell latex in two-stage seeded semi-continuous starved emulsion polymerization process[J].European Polymer Journal,2004(1):89-96. |
| [16] | Stuart C.Thickett;Robert G.Gilbert .Emulsion polymerization:State of the art in kinetics and mechanisms[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(24):6965-6991. |
| [17] | Jeffrey M.Stubbs;Donald C.Sundberg .Core-shell and other multiphase latex particles-confirming their morphologies and relating those to synthesis variables[J].JCT research,2008(2):169-180. |
| [18] | Jeffrey M.Stubbs;Donald C.Sundberg .Fundamental studies on morphology control for latex systems with application to waterborne coatings:the effect of polymer radical mobility in latex particles during polymerization[J].JCT,2003(938):59-67. |
| [19] | Christopher J. Ferguson;Gregory T. Russell;Robert G. Gilbert .Synthesis of latices with hydrophobic cores and poly(vinyl acetate) shells. 2. Use of poly(vinyl acetate) seeds[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(9):2607-2619. |
| [20] | O.J.Karlsson;J.M.Stubbs;D.C.Sundberg;R.H.Carrier .Dynamic Modeling of Non-equilibrium Latex Particle Morphology Development During Seeded Emulsion Polymerization[J].Polymer Reaction Engineering,2003(4):589-625. |
| [21] | Akhmatskaya, E.;Asua, J.M. .Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer[J].Journal of Polymer Science, Part A. Polymer Chemistry,2012(7):1383-1393. |
| [22] | Gonzalezortiz LJ.;Asua JM. .DEVELOPMENT OF PARTICLE MORPHOLOGY IN EMULSION POLYMERIZATION .1. CLUSTER DYNAMICS[J].Macromolecules,1995(9):3135-3145. |
| [23] | Gonzalezortiz LJ.;Asua JM. .DEVELOPMENT OF PARTICLE MORPHOLOGY IN EMULSION POLYMERIZATION .2. CLUSTER DYNAMICS IN REACTING SYSTEMS[J].Macromolecules,1996(1):383-389. |
| [24] | Gonzalezortiz LJ.;Asua JM. .DEVELOPMENT OF PARTICLE MORPHOLOGY IN EMULSION POLYMERIZATION .3. CLUSTER NUCLEATION AND DYNAMICS IN POLYMERIZING SYSTEMS[J].Macromolecules,1996(13):4520-4527. |
| [25] | 孙培勤,刘大壮,赵科,陈甘棠.醋酸乙烯酯-丙烯酸丁酯乳液共聚乳胶粒形态演化过程的模拟[J].高分子学报,1998(05):0. |
| [26] | 赵科,孙培勤,刘大壮.饥饿态半连续VAc/BA核壳乳液聚合乳胶粒形态的演化模拟[J].华东理工大学学报(自然科学版),2004(04):398-401,432. |
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