欢迎登录材料期刊网

材料期刊网

高级检索

采用水电极介质阻挡放电产生的等离子体对聚丙烯进行表面改性,通过接触角测量仪、原子力显微镜、全反射傅里叶红外光谱仪和X射线光电子能谱仪对改性前后聚丙烯表面的各种特性进行表征和分析。结果表明:聚丙烯经过水电极空气等离子体处理后,其表面粗糙度明显增加,处理过程中在聚丙烯表面引入了C-O、C=O和O-C=O等含氧官能团,使其表面接触角下降,表面润湿性提高。

Polypropylene(PP) films were modified by the air plasma produced by water electrode dielec-tric barrier discharge at atmospheric pressure, and the surface characteristics of PP films before and after modification were studied by contact angle measurement, atomic force microscope, Fourier transform infra-red spectroscopy and X-ray photoelectron spectroscopy. The results show that after the PP films was treat-ed by water electrode air plasma, the surface roughness of the PP film increases, and the oxygen-contain-ing functional groups C-O, C=O, and O-C=O are introduced at the surface of PP films, which make the surface contact angle decrease and make the surface wettability increase.

参考文献

[1] Mirabedini S M, Rahimi H, Hamedifara S, et al . Micro-wave Irradiation of Polypropylene Surface:A Study on Wet-tability and Adhesion[J].International Journal of Adhesion and Adhesives,2004,24(2):163-170.,2004.
[2] Chan C M, Ko T M, Hiraoka H . Polymer Surface Modifica-tion by Plasmas and Photons[J].Surface Science Report,1996,24:1-54.,1996.
[3] Kruse A, Krűger G, Baalmann A, et al . Surface Pretreat-ment of Plastics for Adhesive Bonding[J].Journal of Adhe-sion Science and Technology,1995,9(12):1611-1621.,1995.
[4] Mukhopadhyay S M, Joshi P, Datta S, et al . Plasma Assist-ed Surface Coating of Porous Solids[J].Applied Surface Sci-ence,2002,201:219-226.,2002.
[5] 王长全,张贵新,王新新,何湘宁,徐勇.介质阻挡放电改性聚丙烯表面的研究[J].绝缘材料,2011(01):50-54,57.
[6] 杨浩,方志,解向前,戴超.均匀介质阻挡放电改性聚丙烯薄膜的研究[J].绝缘材料,2010(02):57-60,64.
[7] Lopez R, Sanchis R, Garcia D, et al . Surface Characteriza-tion of Hydrophilic Coating Obtained by Low-pressure CH4-O2 Plasma Treatment on a Polypropylene Film[J].Jour-nal of Applied Polymer Science,2009,111(6):2992-2997.,2009.
[8] Cui N Y, Brown N . Modification of the Surface Properties of a Polypropylene(PP)Film Using an Air Dielectric Barri-er Discharge Plasma[J].Applied Surface Science,2002,189:31-38.,2002.
[9] Kwon O J, Myung S W, Lee C S, et al . Comparison of the Surface Characteristics of Polypropylene Films Treated by Ar and Mixed Gas(Ar/O2)Atmospheric Pressure Plasma[J].Journal of Colloid and Interface Science,2006,295(2):409-416.,2006.
[10] Wang C Q, He X N . Polypropylene Surface Modification model in Atmospheric Pressure Dielectric Barrier Discharge[J].Surface and Coatings Technology,2006,201(6):3377-3384.,2006.
[11] 解林坤,黄元波,代沁伶,梁艳君,柴希娟.RF-Ar等离子体对聚乙烯薄膜的表面改性[J].真空科学与技术学报,2012(07):545-549.
[12] 王长全,张贵新,方志,何湘宁,徐勇.常压介质阻挡放电对聚苯乙烯表面改性研究[J].真空科学与技术学报,2009(06):695-699.
[13] Lu X P, Laroussi M . Atmospheric Pressure Glow Dis-charge in Air Using a Water Electrode[J].IEEE Transac-tions on Plasma Science,2005,33(2):272-273.,2005.
[14] Sciarratta V, Vohrer U, Hegemann D, et al . Plasma Func-tionalization of Polypropylene with Acrylic Acid[J].Sur-face and Coatings Technology,2003,174
[15] Socrates G, Infrared and Raman Characteristic Group Fre-quencies Tables and Charts[M]. 3rd Ed. West Sussex:John Wiley & Sons,2001.,2001.
[16] Bellamy L J. The Infra Red Spectra of Complex Molecules [M]. London:Chapman & Hall,1975.,1975.
[17] De Geyter N, Morent R, Leys C . Surface Characterization of Plasma-modified Polyethylene by Contact Angle Experi-ments and ATR-FTIR Spectroscopy[J].Surface and Inter-face Analysis,2008,40:608-611.,2008.
[18] Briggs D. In Practical Surface Analysis[M]. 2nd Ed. Chich-ester:John Wiley,1992.,1992.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%